The proximate and some essential mineral compositions of groundnuts processed by different methods for consumption were determined. The parameters were analyzed using standard methods of the Association of Official Analytical Chemists (AOAC, 2005) and Greenfield and Southgate, 2003. From the results obtained, it was found that the proximate compositions (%) of the groundnuts boiled with the pods were – moisture content (18.77  0.02), crude protein (22.93  0.06), crude fat (38.94  0.03), crude fiber (1.75  0.02), ash (3.90  0.04) and carbohydrate (13.73  0.04). Groundnuts roasted with the pods had– moisture content (2.91  0.04), crude protein (29.73 0.08), crude fat (50.11  0.04), crude fiber (4.36  0.03), ash (5.14  0.03) and carbohydrate (7.76  0.05) while those of the groundnuts roasted without pods were – moisture content (2.88  0.04), crude protein (26.64  0.06), crude fat ss(49.04  0.02), crude fiber (4.26  0.03), ash (4.73  0.02) and the carbohydrate (11.50  0.04). The mineral compositions (in (mg/kg) of the groundnut sample boiled with pods were Na (0.23), K (0.67), Ca (0.11), P (0.38), Mg (0.16) and Fe (41.5). Groundnut samples roasted with the pods were Na (0.38), K (0.98), Ca (0.17), P (0.47), Mg (0.27) and Fe (61.2), while the mineral compositions (in (mg/kg) of the groundnut samples roasted without the pods were Na (0.27), K (0.82), Ca (0.16), P (0.42), Mg (0.25) and Fe (53.6). This study revealed that the proximate and the mineral contents in the roasted samples were generally higher than those of the boiled sample except for the moisture and the carbohydrate contents.

The search for stable and highly efficient solar cell absorbers has revealed interesting materials; however, the ideal solar cell absorber is yet to be discovered. This research aims to explore the potentials of dimethylammonium lead iodide (CH3NH2CH3PbI3) as an efficient solar cell absorber. (CH3NH2CH3PbI3) was modeled from the ideal organic–inorganic perovskite cubic crystal structure and optimized to its ground state. Considering the spin-orbit coupling (SOC) effects on heavy metals, the electronic band structure and bandgaps were calculated using the density functional theory (DFT). In contrast, bandgap correction was achieved by using the GW quasiparticle methods of the many-body perturbation theory. The optical absorption spectra were calculated from the real and imaginary dielectric tensors, which are determined by solving the Bethe–Salpeter equations of the many-body perturbation theory. Spin-orbit coupling induces band splitting and bandgap reduction in both DFT and GW methods, while the GW method improves the DFT bandgap. We report a DFT band gap of 1.55 eV, while the effect of spin-orbit coupling reduces the bandgap to 0.50 eV. Similarly, the self-consistent GW quasiparticle method recorded a bandgap of 2.27 eV, while the effect of spin-orbit coupling on the self-consistent GW quasiparticle method reported a bandgap of 1.20 eV. The projected density of states result reveals that the (CH3NH2CH3PbI3) does not participate in bands around the gap, with the iodine (I) p orbital and the lead (Pb) p orbital showing most prominence in the valence band and the conduction band. The absorption coefficient reaches 106 in the ultraviolet, visible, and near-infrared regions, which is higher than the absorption coefficient of CH3NH3PbI3. The spectroscopic limited maximum efficiency predicts a high maximum efficiency of about 62% at room temperature and an absorber thickness of about 10–1 to 102 μm, suggesting that (CH3NH2CH3PbI3) has an outstanding prospect as a solar cell absorber.

Use of honey is gaining ground worldwide as people are getting aware of the high nutritional values and beneficial health promoting effects of honey. This study was carried out in order to compare the proximate compositions and the mineral contents available in both natural honey and artificial honey obtained from some selected towns in Ijebu and Remo zones of Ogun State, Nigeria. The parameters were analyzed using standard methods of Association of Official Analytical Chemists (AOAC, 2005). From the results obtained, the proximate compositions (%) of the natural honey were - moisture content (17.85±0.74), carbohydrate (78.56±2.92), protein (2.43±0.23), fat (0.68±0.04), crude fiber (0.19±0.02), ash (0.29±0.05) while that of the artificial honey were moisture content (21.65±0.94), carbohydrate (76.25±2.67), protein (1.53±0.12), fat (0.30±0.07), crude fiber (0.12±0.01), ash (0.15±0.09). The natural honey compositions were generally better than those of the artificial honey compositions. This trend was also observed for the mineral contents – Na, K, Ca, Mg, Fe, Zn and other parameters such as pH, titratable acidity, electrical conductivity and total acidity analyzed.