Significant yet untapped resources still abound in the Nigerian sector of the Dahomey Basin. Although the presence of an extensive Cretaceous Petroleum System has been confirmed following recent discoveries in Aje and Ogo Fields offshore Lagos, exploration outputs in the Dahomey Basin has so far not been encouraging. Proper understanding of the basement architectural framework and controls on tectonic development remains key to unlock the unrealised potentials in the basin. Hence, a geophysical interpretation of the basement structure and architecture of the Dahomey Basin southwestern Nigeria has been carried out in this study. Various edge enhancement techniques were applied to the high-resolution residual magnetic intensity (HRRMI) grid of the area. This includes first vertical derivative (FVD), total horizontal derivative (THDR), tilt derivative (TDR) and total horizontal derivative of upward continuation (10 km). Determination of the depth to magnetic sources and sedimentary thicknesses in the study area were achieved using standard Euler deconvolution and source parameter imaging (SPI) techniques, with depth range of 4.5-6.3 km attained in the two identified sub-basins located offshore of the study area. Lineament analysis gave insights on the tectonic trends and stress-field orientation in the basin with major trends in the NNE-SSW, NE-SW, NW-SE, and WNW-ESE directions. 2D forward modelling of some selected profiles was employed to characterise the basement pattern and architecture, which depicted a horstgraben architecture. The basement structure and architecture have a major control on the distribution of sub-basins, petroleum systems elements and trap styles in the basin. The study demonstrates the robust application of high-resolution aeromagnetic data in basin-wide mapping of regional subsurface geological features, basement architecture and determination of sedimentary thickness in a frontier basin.