We demonstrate, theoretically and experimentally, nonbroadening optical beams propagating along any arbitrarily chosen convex trajectory in space. We present a general method to construct such beams, and demonstrate it by generating beams following polynomial and exponential trajectories. We find that all such beams, accelerating along any convex trajectory, display the same universal intensity cross section, irrespective of their acceleration. The universal features of these beams are explored using catastrophe theory.
Under certain conditions, it takes a shorter time to cool a hot system than to cool the same system initiated at a lower temperature. This phenomenon-the "Mpemba effect"-was first observed in water and has recently been reported in other systems. Whereas several detail-dependent explanations were suggested for some of these observations, no common underlying mechanism is known. Using the theoretical framework of nonequilibrium thermodynamics, we present a widely applicable mechanism for a similar effect, the Markovian Mpemba effect, derive a sufficient condition for its appearance, and demonstrate it explicitly in three paradigmatic systems: the Ising model, diffusion dynamics, and a three-state system. In addition, we predict an inverse Markovian Mpemba effect in heating: Under proper conditions, a cold system can heat up faster than the same system initiated at a higher temperature. We numerically demonstrate that this inverse effect is expected in a 1D antiferromagnet nearest-neighbors interacting Ising chain in the presence of an external magnetic field. Our results shed light on the mechanism behind anomalous heating and cooling and suggest that it should be possible to observe these in a variety of systems.
The Mpemba effect is a counter-intuitive relaxation phenomenon, where a system prepared at a hot temperature cools down faster than an identical system initiated at a cold temperature when both are quenched to an even colder bath. Such non-monotonic relaxations were observed in various systems, including water, magnetic alloys, polymers and driven granular gases. We analyze the Mpemba effect in Markovian dynamics and discover that a stronger version of the effect often exists for a carefully chosen set of initial temperatures. In this strong Mpemba effect, the relaxation time jumps to a smaller value leading to exponentially faster equilibration dynamics. The number of such special initial temperatures defines the Mpemba index, whose parity is a topological property of the system. To demonstrate these concepts, we first analyze the different types of Mpemba relaxations in the mean field anti-ferromagnet Ising model, which demonstrates a surprisingly rich Mpemba phase diagram. Moreover, we show that the strong effect survives the thermodynamic limit, and that it is tightly connected with thermal overshoot -in the relaxation process, the temperature of the relaxing system can decay non-monotonically as a function of time. Using the parity of the Mpemba index, we then study the occurrence of the strong Mpemba effect in a large class of thermal quench processes and show that it happens with non-zero probability even in the thermodynamic limit. This is done by introducing the isotropic model for which we obtain analytical lower bound estimates for the probability of the strong Mpemba effects. Consequently, we expect that such exponentially faster relaxations can be observed experimentally in a wide variety of systems.
We study high-order harmonic generation in aligned molecules close to the ionization threshold. Two distinct contributions to the harmonic signal are observed, which show very different responses to molecular alignment and ellipticity of the driving field. We perform a classical electron trajectory analysis, taking into account the significant influence of the Coulomb potential on the strong-field-driven electron dynamics. The two contributions are related to primary ionization and excitation processes, offering a deeper understanding of the origin of high harmonics near the ionization threshold. This Letter shows that high-harmonic spectroscopy can be extended to the near-threshold spectral range, which is in general spectroscopically rich.
Under static conditions, a system satisfying detailed balance generically relaxes to an equilibrium state in which there are no currents. To generate persistent currents, either detailed balance must be broken or the system must be driven in a time-dependent manner. A stationary system that violates detailed balance evolves to a nonequilibrium steady state (NESS) characterized by fixed currents. Conversely, a system that satisfies instantaneous detailed balance but is driven by the time-periodic variation of external parametersalso known as a stochastic pump (SP)-reaches a periodic state with nonvanishing currents. In both cases, these currents are maintained at the cost of entropy production. Are these two paradigmatic scenarios effectively equivalent? For discrete-state systems, we establish a mapping between nonequilibrium stationary states and stochastic pumps. Given a NESS characterized by a particular set of stationary probabilities, currents, and entropy production rates, we show how to construct a SP with exactly the same (time-averaged) values. The mapping works in the opposite direction as well. These results establish a proof of principle: They show that stochastic pumps are able to mimic the behavior of nonequilibrium steady states, and vice versa, within the theoretical framework of discrete-state stochastic thermodynamics. Nonequilibrium steady states and stochastic pumps are often used to model, respectively, biomolecular motors driven by chemical reactions and artificial molecular machines steered by the variation of external, macroscopic parameters. Our results loosely suggest that anything a biomolecular machine can do, an artificial molecular machine can do equally well. We illustrate this principle by showing that kinetic proofreading, a NESS mechanism that explains the low error rates in biochemical reactions, can be effectively mimicked by a constrained periodic driving.
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