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Elemental composition of the inorganic fraction, carbon isotopes, and C/N of organic matter from a new radiocarbon-dated sedimentary sequence collected from Lake Coatetelco (960 m asl) extend information about the environmental and hydrological conditions of central Mesoamerica from the earliest Holocene to the interval of first human settlements in the lake vicinity and nearby streams. Proxy-based reconstructions of erosion/runoff (Ti), water column salinity (CaCO3), sediment–water interactions (PIA), and provenance of organics (δ13Corg and C/N) showed similarities with the summer insolation modulated ITCZ position between ∼11.5 and 4.2 cal ka BP, and more frequent ENSO between ∼4.2 and 2.1 cal ka BP. After a possible depositional hiatus between ∼11.2 and 10.2 cal ka BP, the moderate-to-extremely altered sediments were deposited with enhanced erosion/runoff during the wetter ∼10.2–6 cal ka BP and the organic matter was dominantly autochthonous. Comparison of δ13Corg and C/N suggested that the contribution of C4 plants to organic matter increased over the drier ∼6–4.2 cal ka BP. Sediments representing this middle- Holocene drought-like condition showed geochemical similarity with sediments of the Post-Classic drought (∼1–0.4 cal ka BP), coeval with abandonment of the Xochicalco culture. Variation in seasonal insolation at orbital scales might have forced frequent droughts between ∼6 and 4.2 cal ka BP and the ENSO related short-lived storms possibly led to an unstable hydroclimate after ∼4.2 cal ka BP when the first Olmec settlements commenced in the region. Dissimilarity between this lacustrine archive and speleothems from southwest Mexico for the later part of the Holocene reflected different sensitivities of the geological records to seasonal and-annual precipitation.

With an increasing reduction of hydrological resources across Mexico and their growing contamination due to global warming and anthropogenic activities, this study evaluated water from the perennial Lake Coatetelco (Ca–Mg–HCO3) in tropical central-southern Mexico and groundwater (Ca–Mg–HCO3 and Na–HCO3–Cl) from the surrounding wells for drinking as well as irrigation qualities. Comparison with the WHO guidelines, and the estimated water quality indices (DWQI and IWQI) grouped almost all the samples collected after the warm season rainfall in excellent and good categories (DWQI < 100) for drinking, even though fluoride remained > 1.5 mg/L in 50% samples. Except for one groundwater sample, all showed > 25% permeability (classes I and II) in Donnen classification indicating their suitability for irrigation. USSL and Wilcox classifications, however, catalogued some in the high-salinity hazard group and some as doubtful for irrigating regular plants. Samples from about 53% wells are also in high and severe restriction irrigation categories of IWQI. Total Hazard Quotient Index (THQI) of non-carcinogenic risk results (HQfluoride>1) shows that at least one lake water sample and 47% of groundwater might expose both adult and child population to possible risk of dental and skeletal fluorosis. This baseline information about water quality might be useful for both the short- and long-term monitoring and evaluation in this region.

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