The ternary system SrO-CeO,-TiO, was investigated using X-ray diffractometry. The formation of a new compound, Sr,Ce,Ti,O,,, was established, and its compatibilities with SrO, SrCeO,, and SrTiO, were studied. The results revealed the existence of a series of compounds Sr,-,,Ce,Ti,O,, and solid solutions Sr,+,Ce,Ti,+,O,,+,, (n I 6).