The coherent photogalvanic effect leads to the generation of a current under the absorption interference of coherent beams and allows for the inscription of space‐charge gratings leading to a second‐order susceptibility (χ(2)). The inscribed grating automatically results in quasi‐phase‐matching between the interfering beams. Theoretical and experimental studies, considering the degenerate case of second‐harmonic generation, show significant conversion efficiency enhancements. However, the link between the theory and experiment is not fully established such that general guidelines and achievable conversion efficiency for a given material platform are still unclear. In this work, the phenomenological model of coherent photogalvanic effect in optical waveguides is theoretically analyzed. This model predicts the existence of non‐degenerate sum‐frequency generation quasi‐phase‐matching gratings, which is confirmed experimentally for the first time. Furthermore, the time dynamics of the space‐charge grating inscription in coherent photogalvanic process is formulated. Based on the developed theoretical equations, the material parameters governing the process for stoichiometric silicon nitride are extracted. The results obtained provide a basis to compare the performances and potentials of different platforms. This work not only supplements the theory of coherent photogalvanic effect, but also enables us to identify critical parameters and limiting factors for the inscription of χ(2) gratings.

The availability of nonlinear parametric processes, such as frequency conversion in photonic integrated circuits is essential. In this contribution, we demonstrate a highly tunable second-harmonic generation in a fully complementary metal–oxide–semiconductor (CMOS)-fabrication-compatible silicon nitride integrated photonic platform. We induce the second-order nonlinearity using an all-optical poling technique with the second-harmonic light generated in the fundamental mode, and a narrow quasi-phase matching (QPM) spectrum by avoiding higher-order mode mixing. We are then able to broadly tune the phase-matched pump wavelength over the entire C-band (1540 nm to 1560 nm) by varying the poling conditions. Fine-tuning of QPM is enabled by thermo-optic effect with the tuning slope Δ λ / Δ T in our device being 113.8 pm/°C. In addition, we exploit the measurable variation of the 3 dB QPM bandwidth to confirm how the length of the all-optically inscribed grating varies with exposure time.

Quasi-phase-matching (QPM) has become one of the most common approaches for increasing the efficiency of nonlinear three-wave mixing processes in integrated photonic circuits. Here, we provide a study of dispersion engineering of QPM second-harmonic (SH) generation in stoichiometric silicon nitride ( Si 3 N 4 ) waveguides. We apply waveguide design and lithographic control in combination with the all-optical poling technique to study the QPM properties and shape the waveguide dispersion for broadband spectral conversion efficiency inside Si 3 N 4 waveguides. By meeting the requirements for maximal bandwidth of the conversion efficiency spectrum, we demonstrate that group-velocity matching of the pump and SH is simultaneously satisfied, resulting in efficient SH generation from ultrashort optical pulses. The latter is employed for retrieving a carrier-envelope-offset frequency of a frequency comb by using an f − 2 f interferometric technique, where supercontinuum and SH of a femtosecond pulse are generated in Si 3 N 4 waveguides. Finally, we show that the waveguide dispersion determines the QPM wavelength variation magnitude and sign due to the thermo-optic effect.

Silicon nitride (Si 3 N 4 ) is an ever-maturing integrated platform for nonlinear optics but mostly considered for third-order [χ (3) ] nonlinear interactions. Recently, second-order [χ (2) ] nonlinearity was introduced into Si 3 N 4 via the photogalvanic effect, resulting in the inscription of quasi-phase–matched χ (2) gratings. However, the full potential of the photogalvanic effect in microresonators remains largely unexplored for cascaded effects. Here, we report combined χ (2) and χ (3) nonlinear effects in a normal dispersion Si 3 N 4 microresonator. We demonstrate that the photo-induced χ (2) grating also provides phase-matching for the sum-frequency generation process, enabling the initiation and successive switching of primary combs. In addition, the doubly resonant pump and second-harmonic fields allow for effective third-harmonic generation, where a secondary optically written χ (2) grating is identified. Last, we reach a broadband microcomb state evolved from the sum-frequency–coupled primary comb. These results expand the scope of cascaded effects in microresonators.

Integrated entangled photon-pair sources are key elements for enabling large-scale quantum photonic solutions and address the challenges of both scaling-up and stability. Here we report the first demonstration of an energy-time entangled photon-pair source based on spontaneous parametric down-conversion in silicon-based platform–stoichiometric silicon nitride (Si3N4)–through an optically induced second-order (χ(2)) nonlinearity, ensuring type-0 quasi-phase-matching of fundamental harmonic and its second-harmonic inside the waveguide. The developed source shows a coincidence-to-accidental ratio of 1635 for 8 µW pump power. We report two-photon interference with remarkable near-perfect visibility of 99.36±1.94%, showing high-quality photonic entanglement without excess background noise. This opens a new horizon for quantum technologies requiring the integration of a large variety of building functionalities on a single chip.