Waters of the eastern Mediterranean portray an unusual pattern of stable isotope composition compared with other evaporitic systems: an increase in 18O concentration up to value of δ18O = +2.2‰ is not matched by a commensurate increase of deuterium. It is shown that this unusual pattern is an expression of the “medi‐terranean” location of the sea, where the air‐sea interaction with relatively dry and isotopically depleted continental air masses dominates the evaporation process in winter and where the diluting meteoric waters are extremely depleted in the heavy isotopes. As a result, the slope of the evaporation line in δ(2H)‐δ(18O) space is lower than in other marine systems, whereas the mixing line between the meteoric waters and the seawater is very steep. This pattern provides an independent method for the estimation of the evaporation E and freshwater influx terms M of the water balance of the Mediterranean Sea. In winter, the ratio of evaporation to freshwater input is found to be E/M = 1.20, whereas in summer this ratio E/M = 1.83.
Extensive data sets on surface chlorophyll a (chl a), depth-integrated primary production (DIPP) and phosphate (PO 4 , µM) averaged for the upper 25 m layer in 1964, 1973, 1978 and for a period (1980 to 1996) of regular measurements have been used to evaluate long-term changes in the upper portion of the euphotic layer of the entire open (>1000 m) Black Sea. After preliminary analysis of seasonal dynamics, special attention was given to data obtained during those periods of the year with relatively stable values, revealing interannual and long-term fluctuations and trends. Of 2 phytoplankton characteristics (chl a and DIPP), long-term trends were obtained only for chl a since only these data covered the entire open sea and all periods investiged. A positive correlation was found between DIPP (using 2 different 14 C methods: actual in situ and simulated in situ) and the more numerous chl a data for different monthly intervals, with significant correlation coefficients (r = 0.51 to 0.82). This means that the observed patterns in long-term variability for chl a may be valid also for DIPP. The results show that interannual fluctuations in chl a are more pronounced during the warm months, from approximately May to September. Chl a levels within this interval were moderate, with a mean of 0.15 ± 0.04 mg m -3 during the first 'quiet' period (1964 to 1986), but increased steadily at a rate of 0.06 mg m
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