By adding soy flour (soy) to linear low‐density polyethylene (LLDPE), soy‐PE fibers with enhanced hydrophilic characteristics were developed. Blends containing only soy and LLDPE had limited draw‐down, and the resulting thick fibers showed poor mechanical properties. When monoglyceride was added as a compatibilizer, thin fibers with good properties could be successfully spun due to improved dispersion of soy agglomerates in the LLDPE melt. Fibers spun from a blend containing 23/7/70 wt % of soy‐monoglyceride‐LLDPE displayed a tensile modulus and strength of 615 ± 38 and 57 ± 8 MPa, respectively. At 30% less synthetic content, these fibers still displayed mechanical properties generally comparable to those of base polyethylene fibers. Contact angle measurements showed that the soy‐based fibers had a hydrophilic surface (contact angle of 33° ± 4°). Moisture absorption studies confirmed that soy‐PE fibers gained about 20 wt % moisture in 1 h, whereas neat LLDPE fibers did not absorb any significant amount (LLDPE is hydrophobic). This hydrophilic behavior of soy‐PE fibers mimics that of natural fibers. Presence small soy agglomerates on the fiber surface also provides a textured surface and a desired tactile feel to the soy‐PE fibers, which coupled with hydrophilic behavior indicates their potential use in disposable nonwovens. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46609.
Poly(lactic acid) (PLA) has a significant potential as a biodegradable polymer, but its high cost and slow biodegradability restrict its use in disposable products. This study establishes a novel route to accomplish both objectives by the addition of low‐cost soy fillers into PLA, which reduced material cost and increased the degradation rate of resulting soy‐PLA fibers. Due to partial thermal degradation of soy fillers at PLA melt temperature, they could be melt‐compounded into PLA up to 5 wt%. Fine continuous fibers (D ∼ 25‐50 μm) were successfully produced via melt spinning, and further melt‐consolidated into prototypical nonwovens. The tensile strength of soy‐PLA fibers containing soy reside and soy flour were 56 ± 9 and 44 ± 5 MPa, respectively. Although slightly lower than that of neat PLA fibers (74 ± 2 MPa), the fibers possessed adequate tenacity for use as nonwoven fabrics. Fiber modulus remained unaffected at about 2.5 GPa. The soy‐PLA fibers displayed a relatively rough exterior surface and provided a natural‐fiber feel. The overall degradation of soy‐PLA fibers was accelerated about 2‐fold in a basic medium due to the preferential dissolution of soy that led to increased surface area within the PLA matrix indicating their potential for use in biodegradable nonwovens.
Polypropylene (PP) fibers are heavily used in disposable nonwovens fabrics because of their desirable properties and low-cost, but they are not biodegradable. With the goal of reducing non-biodegradable plastic waste in the environment, the primary aim of this study was to produce fibers with reduced content of PP for disposable fabrics by incorporating soy flour, a bio-based renewable material. An optimum processing temperature of 190 °C was established, and thin fibers with a diameter under 60 µm were successfully melt-spun. Inclusion of compatibilized soy (SFM) at 30 wt% resulted in fibers with a tensile modulus of 674 ± 245 MPa and a yield strength of 18 ± 4 MPa. At 15 wt% SFM, fiber tensile modulus and yield strength were 914 ± 164 and 29 ± 3, respectively. Although lower than those of neat PP fibers (1224 ± 136 MPa and 37 ± 3 MPa), these SFM/PP fiber properties are suitable for nonwoven applications. Additionally, partial presence of soy particulates on fiber surface imparted enhanced water absorption and colorability properties to the fibers while imparting the fibers the feel of natural fibers.Although more difficult to produce, soy-PP fibers possessed similar properties as compared to those of than soy-PE fibers reported in earlier studies.
With shrinking size of electronic devices, increasing performance and accompanying heat dissipation, there is a need for efficient removal of this heat through packaging materials. Polymer materials are attractive packaging materials given their low density and electrical insulating properties, but they lack sufficient thermal conductivity that inhibits heat transfer rate. Hexagonal boron nitride (BN) possesses excellent thermal conductivity and is also electrically insulating, therefore BN-filled polymer composites were investigated in this study. Results showed successful continuous extrusion of BN-filled linear low-density polyethylene through micro-textured dies that is a scalable manufacturing process. Through-thickness thermal conductivity measurements established that 30 vol% BN content led to an over 500% increase in thermal conductivity over that of pure polymer. Textured film surface provided about a 50% increase in surface area when compared with non-textured films. This combination of increased surface area and enhanced thermal conductivity of BN-filled textured films indicates their potential application for improved convective thermal transport.
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