A metrological assessment of grating-based optical fiber sensors is proposed with the aim of providing an objective evaluation of the performance of this sensor category. Attention was focused on the most common parameters, used to describe the performance of both optical refractometers and biosensors, which encompassed sensitivity, with a distinction between volume or bulk sensitivity and surface sensitivity, resolution, response time, limit of detection, specificity (or selectivity), reusability (or regenerability) and some other parameters of generic interest, such as measurement uncertainty, accuracy, precision, stability, drift, repeatability and reproducibility. Clearly, the concepts discussed here can also be applied to any resonance-based sensor, thus providing the basis for an easier and direct performance comparison of a great number of sensors published in the literature up to now. In addition, common mistakes present in the literature made for the evaluation of sensor performance are highlighted, and lastly a uniform performance assessment is discussed and provided. Finally, some design strategies will be proposed to develop a grating-based optical fiber sensing scheme with improved performance.

The synthesis of carbon nanoparticles obtained by direct laser ablation [UV pulsed laser irradiation (248 nm, KrF)] of carbon targets immersed in water is described. Laser ablation features were optimized to produce carbon nanoparticles with dimensions up to about 100 nm. After functionalization with NH 2-polyethylene-glycol (PEG 200) and N-acetyl-l-cysteine (NAC) the carbon nanoparticles become fluorescent with excitation and emission wavelengths at 340 and 450 nm, respectively. The fluorescence decay time was complex and a three-component decay time model originated a good fit (= 1.09) with the following lifetimes: 1 = 0.35 ns; 2 = 1.8 ns; and 3 = 4.39 ns. The fluorescence of the carbon dots is sensitive to pH with an apparent pK a = 4.2. The carbon dots were characterized by 1 H NMR and HSQC and the results show an interaction between PEG 200 and the carbon surface as well as a dependence of the chemical shift with the reaction time. The fluorescence intensity of the nanoparticles is quenched by the presence of Hg(II) and Cu(II) ions with a Stern-Volmer constant (pH = 6.8) of 1.3 × 10 5 and 5.6 × 10 4 M −1 , respectively. As such the synthesis and application of a novel biocompatible nanosensor for measuring Hg(II) is presented.

The proposed sensing device relies on the self-imaging effect that occurs in a pure silica multimode fiber (coreless MMF) section of a single-mode-multimode-single-mode (SMS)-based fiber structure. The influence of the coreless-MMF diameter on the external refractive index (RI) variation permitted the sensing head with the lowest MMF diameter (i.e., 55 μm) to exhibit the maximum sensitivity (2800  nm/RIU). This approach also implied an ultrahigh sensitivity of this fiber device to temperature variations in the liquid RI of 1.43: a maximum sensitivity of -1880  pm/°C was indeed attained. Therefore, the results produced were over 100-fold those of the typical value of approximately 13  pm/°C achieved in air using a similar device. Numerical analysis of an evanescent wave absorption sensor was performed, in order to extend the range of liquids with a detectable RI to above 1.43. The suggested model is an SMS fiber device where a polymer coating, with an RI as low as 1.3, is deposited over the coreless MMF; numerical results are presented pertaining to several polymer thicknesses in terms of external RI variation.

Recent advances in the application of semiconductor nanocrystals, or quantum dots, as biochemical sensors are reviewed. Quantum dots have unique optical properties that make them promising alternatives to traditional dyes in many luminescence based bioanalytical techniques. An overview of the more relevant progresses in the application of quantum dots as biochemical probes is addressed. Special focus will be given to configurations where the sensing dots are incorporated in solid membranes and immobilized in optical fibers or planar waveguide platforms.

Nafion has been evaluated as a sensing phase of an optical fibre humidity sensor based on a low-finesse Fabry-Perot interferometer. The sensor was constructed by manual deposition of a drop of a Nafion solution on the tip of a single mode optical fibre, forming a Fabry-Perot resonant cavity. The absorption of water by the Nafion film makes it swells, changing its refractive index and the length of the cavity, which produces a phase shift in the interference signal. The sensitivity, stability and response time of the sensor were evaluated in the RH range from 22 to 80% by analysing the correspondent reflection spectra of the interference fringes. As a result, it was obtained that Nafion can be used as sensing phase of an optical fibre humidity sensor based on optical fibre Fabry-Perot interferometry, presenting a response time of 242 ms (3% RH variation) and a sensitivity of 3.5 nm/%RH.