Reactions of Primary Amines and Alcohols with 4-Toluoyl Azide. -The reaction of toluoyl azide with primary amines in non-nucleophilic solvents gives the corresponding toluoyl amides, while in the presence of alcohols the concurrent formation of esters occurs (kinetic investigation). -(ULBRICHT, M.; BOEHME, P.; HARTMANN, U.; Monatsh.
Die Methylchinoxaline (I) werden über die Pyridiniumiodide in die Nitrone übergeführt (mit p‐Nitroso‐N,N‐dimethyl‐anilin in Methanol in Gegenwart von Na,CO3, kristallin isoliert), deren saure Spaltung die Aldehyde (II) gibt.
The η3‐allyl‐Ni(II) borates (I) react with hexa‐1,5‐diene (II) by an insertion reaction into the allyl‐Ni bond to give the corresponding title complexes (III).
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