Image Matching2)D. LEPSKI and P. BURCKThe elastic distortions and the TEM contrast due to metastable molybdenum carbide particles of unknown structure in molybdenum are computed, using previous results, by means of that tensor of generating stress-free strain which has been derived in Part I from a physical model in terms of various structure parameters. By comparison of electron micrographs with calculated images the model is confirmed and parameters are fitted. This method does not require large precipitate volume fractions as SAD or highly resolved images and extremely thin foils as lattice fringe imaging. The phase considered is proved to be a semicoherent carbide of the composition MoC1 --z with f.c.c. structure and the lattice parameter 0.43 nm, which forms flat lenticular discs on { 114) planes. Die elastischen Verzerrungen und der TEM-Kontrast durch metastabile Molybdankarbidteilchen unbekannter Struktur in Molybdan werden unter Verwendung friiherer Ergebnisse mit Hilfe des Tensors der erzeugenden spannungsfreien Deformation berechnet, der in Teil I aus einem physikalischen Modell als Funktion verschiedener Strukturparameter abgeleitet worden war. Der Vergleich elektronenmikroskopischer Aufnahmen mit simulierten Beugungskontrastbildern bestatigt das Modell und ermoglicht die Bestimmung von Strukturparametern. Diese Methode erfordert weder einen groBen Volumenanteil der zweiten Phase wie die Feinbereichsbeugung noch hochaufgeloste Bilder und extrem dunne Folien wie die Netzebenenabbildung. Die untersuchte Phase erweist sich a h ein teilkoharentes Karbid der Zusammensetzung MoCl--z mit k.f.z. Struktur und der Gitterkonstante 0,43 nm, das flache linsenformige Scheibchen auf { 114) -Ebenen bildet.
The formation of the thermodynamically stable incoherent Mo2C precipitates during aging of quenched carbon‐doped molybdenum crystals proceeds through a sequence of metastable intermediate phases. For such a carbide with unknown structure the tensor of inelastic strain due to the phase transition from the metal to the carbide is constructed on the basis of a physically reasonable model allowing for a partial loss of coherency. From that strain tensor, which depends on several structure parameters, the elastic distortions around the particles and the electron diffraction contrast can be calculated. Most of the unknown parameters will be determined in a subsequent paper by comparing the theoretical images with corresponding electron micrographs.
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