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The sulfur-iodine cycle is one of the most promising thermochemical cycles for hydrogen production. Its coupling with a solar energy primary source is a great challenge to achieve efficient and economically competitive H 2 production. Within this cycle, the decomposition of sulfuric acid plays a key role, with this process being the most energy-demanding reaction step. In this paper, a combined computational and experimental study of the decomposition at high temperature of H 2 SO 4 to SO 2 is presented. The scope of this paper is to present new information and data about the experimental high-temperature decomposition of sulfuric acid carried out in a solar reactor in view of a possible industrial exploitation of this reaction. Starting from a new complete thermodynamic modeling of the process, carried out by investigating the effect of the pressure and the temperature on the SO 2 conversion rates, the study of the high-temperature decomposition of H 2 SO 4 by direct solar radiation using a Fe 2 O 3 -based catalyst was carried out for the first time. The modeling and experimental results obtained are discussed together with the available literature. In summary, SO 2 conversion yields close to thermodynamic predictions were obtained in the temperature range 1050-1200 K at a starting sulfuric acid partial pressure of p ) 0.61 bar.

A polymer-surfactant complex (OTAPA) was prepared by titration of aqueous poly(sodium acrylate) with stoichiometric amounts of octadecyltrimethylammonium chloride. The resulting product is not water-soluble and does not dissolve in most polar and nonpolar, liquids. OTAPA has peculiar thermal behaviour and interesting structural properties. It has a high melting temperature and decomposes around 350 degreesC. According to preliminary X-ray findings, the complex is formed by an arrangement of alkyl chains around the polymer skeleton, packed into a layered structure. The complex forms an elastic gel in ethylene glycol, and, to a much lesser extent, in glycerol or tetrahydrofuran, but is hardly water-soluble. Indeed, the occurrence of micelle-assisted dissolution and the precipitation of OTAPA from such mixtures, upon dilution with water, have been observed. Applications of OTAPA as a hydrophobic modifier of surfaces can be considered

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