Calculated X-ray diffraction pattern data for diamond polytypes are presented, which provides the required parameters for the characterization of the proposed diamond polytypes. The literature on diamond polytypes contains some small but significant errors with respect to the details of the crystal structure, including space groups, the atom positions in the unit cell, and the atomic layer stacking. In this paper, the crystal structures of four different hexagonal diamond and two different rhombohedral diamond polytypes are theoretically calculated to provide correct crystallographic information with which the diamond polytypes in a given sample can be characterized. [
The effect of 15 vol% particulate diamond reinforcement on the thermal conductivity of a cordierite matrix was studied as a function of diamond particle size from room temperature to 700°C. The thermal conductivity was found to increase with increasing particle size to a maximum increase of about 75% for a mean particle size of 50 pm. The particle size effect was found to be more pronounced at the lower temperatures than at the higher temperatures. The observed effect of particle size and temperature was attributed to the existence of an interfacial thermal barrier, possibly resulting from interfacial phonon scattering, with a positive temperature dependence of the interfacial thermal conductance. The magnitude of this conductance suggested strong adhesion between the diamond and cordierite.
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