P. Diversi scite author profile

The aggregation states in solution of gold(I) cationic complexes of the formula [Au2(StBu)(L2)][BF4] (L = PMe3, PEt3, PtBu3, PPh3; L2 = dppm, dppe) were studied by MS (ESI) and DOSY spectroscopy. These compounds are tetranuclear in the solid state with a core of four gold centres bound together by aurophilic interactions and bridging thiolato groups. Some of these tetranuclear systems are maintained intact in solution depending on the phosphane steric properties or denticity

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The reaction of benzene with diethylamine in the presence of an iridium(I)/mercury(II) based system: a model route for the direct amination of aromatic hydrocarbons

Diversi

Ermini

Ingrosso

et al. 1995

Journal of Organometallic Chemistry

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P. Diversi

Electron Transfer Catalysis in the Activation of C-H Bonds by Iridium Complexes

Rhodium-catalyzed synthesis of pyridines from alkynes and nitriles

Electronic and steric effects in the rhodium-complex catalysed co-cyclization of alkynes and nitriles to pyridine derivatives

Cationic Gold(I) Phosphanyl Thiolates: Aurophilic Interactions in the Solid State and in Solution

The reaction of benzene with diethylamine in the presence of an iridium(I)/mercury(II) based system: a model route for the direct amination of aromatic hydrocarbons

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