SummaryThe coupling of glass capillary supercritical fluid chromatography to a high temperature GC/MS system via a micrometeradjustable glass capillary interface including an integrated pressure restrictor is described. With this coupling device, both complementary capillary chromatographic methods retain their full independence and flexibility.It is shown that in supercritical fluid chromatographyglassfulfils all the requirements of a suitable support material. The preparation of narrow bore glass capillary columns (0.06 mm i.d.),coatedwithchemicallybondedandcrosslinkedfluidswitha film thickness of about 0.6 p, which exploit the merits of OHterminated polysiloxanes as stationary phases is discussed. The application of glass capillary SFC is demonstrated and compared with examples given in the literature.