No abstract

A continuous record of atmospheric lead since 12,370 carbon-14 years before the present (14C yr BP) is preserved in a Swiss peat bog. Enhanced fluxes caused by climate changes reached their maxima 10, 590 (14)C yr BP (Younger Dryas) and 8230 (14)C yr BP. Soil erosion caused by forest clearing and agricultural tillage increased lead deposition after 5320 (14)C yr BP. Increasing lead/scandium and decreasing lead-206/lead-207 beginning 3000 (14)C yr BP indicate the beginning of lead pollution from mining and smelting, and anthropogenic sources have dominated lead emissions ever since. The greatest lead flux (15.7 milligrams per square meter per year in A.D. 1979) was 1570 times the natural, background value (0.01 milligram per square meter per year from 8030 to 5320 (14)C yr BP).

This paper reviews the 210Pb dating programme carried out at the University of Liverpool over a period of three decades since its inception by Frank Oldfield in the mid-1970s. The work at Liverpool has included studies of the basic processes controlling the supply of 210Pb to the various natural archives, as well as the development of a detailed and systematic methodology for dating the environmental records in these archives. The assumption that 210Pb fallout at any given location is constant when measured on timescales of a year or more has been tested using data on 210Pb concentrations in UK rainwater spanning more than 40 years, and a simple atmospheric model developed to account for observed spatial variations in the flux over large land masses. The basic assumptions of the CRS dating model have been tested in detail using mass balance studies of fallout radionuclides in catchment/lake systems, and in general using data from a large number of separate studies. The Liverpool data base is used to illustrate the wide ranging applicability of the 210Pb dating method. Results are shown from lakes varying in size from the very small to the very large, and with sedimentation rates ranging from the very fast to the very slow. The particular difficulties of dating sediment records from Desert Lakes and Polar Regions with very low atmospheric fluxes are discussed, with unexpected results in some cases.