A critical review of the very long-standing problem of the diffuse interstellar bands is presented with emphasis on spectroscopic aspects of observational, modelling and laboratory-based research. Some research themes and ideas that could be explored theoretically and experimentally are discussed. The article is based on the Journal of Molecular Spectroscopy Review Lecture presented at the 60th Ohio State University International Symposium on Molecular Spectroscopy, June 2005.

Aims. In order to gain new insight into the unidentified identity of the diffuse interstellar band (DIB) carriers, this paper describes research into possible links between the shape of the interstellar extinction curve (including the 2175 Å bump and far-UV rise), the presence or absence of DIBs, and physical and chemical conditions of the diffuse interstellar medium (gas and dust) in the Small Magellanic Cloud (SMC). Methods. We searched for DIB absorption features in VLT/UVES spectra of early-type stars in the SMC whose reddened lines-ofsight probe the diffuse interstellar medium of the SMC. Apparent column density profiles of interstellar atomic species (Na i, K i, Ca ii and Ti ii) are constructed to provide information on the distribution and conditions of the interstellar gas.Results. The characteristics of eight DIBs detected toward the SMC wing target AzV 456 are studied and upper limits are derived for the DIB equivalent widths toward the SMC stars AzV 398, AzV 214, AzV 18, AzV 65 and Sk 191. The amount of reddening is derived for these SMC sightlines, and, using R V and the H i column density, converted into a gas-to-dust ratio. From the atomic column density ratios we infer an indication of the strength of the interstellar radiation field, the titanium depletion level and a relative measure of turbulence/quiescence. The presence or absence of DIBs appears to be related to the shape of the extinction curve, in particular with respect to the presence or absence of the 2175 Å feature. Our measurements indicate that the DIB characteristics depend on the local physical conditions and chemical composition of the interstellar medium of the SMC, which apparently determine the rate of formation (and/or) destruction of the DIB carriers. The UV radiation field (via photoionisation and photo-destruction) and the metallicity (i.e. carbon abundance) are important factors in determining diffuse band strengths which can differ greatly both between and within galaxies.

The Large Magellanic Cloud (LMC) offers a unique laboratory to study the diffuse interstellar bands (DIBs) under conditions that are profoundly different from those in the Galaxy. DIB carrier abundances depend on several environmental factors, in particular the local UV radiation field. In this paper we present measurements of twelve DIBs in five lines of sight to early-type stars in the LMC, including the 30 Doradus region. From the high resolution spectra obtained with VLT/UVES we also derive environmental parameters that characterise the local interstellar medium (ISM) in the probed LMC clouds. These include the column density components (including total column density) for the atomic resonance lines of Na i, Ca ii, Ti ii, K i. In addition, we derive the H i column density from 21 cm line profiles, the total-to-selective visual extinction R V and the gas-to-dust ratio N(H i)/A V . Furthermore, from atomic line ratios we derive the ionisation balance and relative UV field strength in these environments. We discuss the properties of the LMC ISM in the context of DIB carrier formation. The behaviour of DIBs in the LMC is compared to that of DIBs in different local environmental conditions in the Milky Way. A key result is that in most cases the diffuse band strengths are weak (up to factor 5) with respect to Galactic lines of sight of comparable reddening, E B−V . In the line of sight towards Sk -69 223 the 5780 and 5797 Å DIBs are very similar in strength and profile to those observed towards HD 144217, which is typical of an environment exposed to a strong UV field. From the velocity analysis we find that DIB carriers (towards Sk -69 243) are better correlated with the ionised species like Ca ii than with neutrals (like Na i and CO). The most significant parameter that governs the behaviour of the DIB carrier is the strength of the UV field.

Detection of Diffuse Interstellar Bands in the Magellanic Clouds Ehrenfreund, P.; Cami, J.; Jimenez-Vicente, J.; Foing, B.H.; Kaper, L.; van der Meer, A.; Cox, N.L.J.; d' Hendecourt, L.; Maier, J.P.; Salama, F.ABSTRACT With the Ultraviolet Visual Echelle Spectrograph mounted at the Very Large Telescope, we have observed at unprecedented spectral resolution the absorption spectrum toward reddened stars in the Magellanic Clouds over the wavelength range of 3500-10500 Å . This range covers the strong transitions associated with neutral and charged large carbon molecules of varying sizes and structures. We report the first detection of diffuse interstellar bands (DIBs) at 5780 and 5797 Å in the Small Magellanic Cloud and the variation of the 6284 Å DIB toward several targets in the Large Magellanic Cloud. The variation of DIBs in the Magellanic Clouds compared with Galactic targets may be governed by a combination of the different chemical processes prevailing in low-metallicity regions and the local environmental conditions.

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C + 60 ) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C + 60 requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C + 60 9348, 9365, 9428 and 9577 Å absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C + 60 bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C + 60 bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C + 60 .