The procedure used to determine polychlorinated biphenyls (PCBs), polychlorinated terphenyls (PCTs), chlorinated dibenzodioxins, and chlorinated dibenzofurans is outlined in Table 1. It is based on the cleanup-chromatography of Holden and Marsden (1), modified as described (2). Most PCBs are eluted in fraction I. Fraction II contains some PCBs, p , p'-DDE, and PCTs, whereas heptachlor exposide, dieldrin, endrin, p,p'-DDD, and p , p'-DDT are eluted in fraction III. Fractions I and II are further chromatographed on alumina, essentially according to Porter and Burke (3), to determine chlorinated dibenzodioxins and dibenzofurans. PCTs, hexaand octachlorodibenzodioxin, and octachlorodibenzofuran were quantified by gas chromatography on 3% OV-210 on Chromosorb WAW 60/80 in a 6 ft X 4 mm column at 200°C. A 4% SE-30 column was used to quantify PCBs, chlorinated hydrocarbon pesticides, 2,3,7, 8-tetrachlorodibenzodioxin, di-, tri-, and tetrachlorodibenzofuran. Recovery of PCBs and chlorinated hydrocarbon

This study aimed to evaluate the discharge characteristics of nonylphenol (NP) and octylphenol (OP) in the effluent of wastewater treatment facilities in the southern Gyeonggi-do. The detection rates of NP and OP were found to be 39.3% and 43.1%, respectively, with median values ranging from 1 to 3 μg/L across all industries. The industries that showed a detection rate of 50% or more were car wash, chemical experiment, fabric leather, paper wood, and plating facilities, with rates ranging from 50% to 75%, while other industries had detection rates of 21.7% to 36.8%. In terms of facility size, small-size establishments such as Type 4 and Type 5 showed higher detection rates in the "Na" region where somewhat relaxed standards are applied on a regional basis. This is because the proportion of Type 4 and Type 5 industries, including various concentration distributions of chemical experiments, research facilities, car washes, petrochemical, and plating industries, is higher than 77.7% overall and concentrated at a rate of 55.6% or higher in the “Na” region. Furthermore, the correlation coefficient (R) between NP and OP exhibited moderate association with values of 0.45 and 0.60 for car washes and plating industries, respectively. Chemical experiments, paper and wood, electrical and electronic, and medicine and hospital facilities showed strong association with correlation coefficients of 0.83, 0.82, 0.82, and 0.79, respectively. The findings in this study can be expected to serve as fundamental data for NP and OP in the establishment of water quality pollutants designation and discharge standards (draft) currently being pursued.

A median mortality of 120 ± 30 days occurred among juvenile Atlantic salmon (Salmo salar), fed dry fish food containing 2.7, 5.7, 2.8, and 9.1 uMg/g wet weight of 2,8-di-, tri-, tetra-, and octachlorodibenzofuran, respectively (1). Only octachlorodibenzofuranx was detected in the dead fish, and the level was 0.03 ug/g in the muscle and 0.21 ,Ag/g in the gut (both values on wet weight basis). The fate of the lower chlorinated dibenzofurans was not known and additional experiments, described in this paper, were carried out with immature brook trout (Salvelinus fontinalis), fed relatively high levels of 2,8-dichlorodibenzofuran. ExperimentalThe preparation of 2,8-dichlorodibenzofuran was carried out as described (2). Three crystallizations were necessary to remove tri-and tetrachlorodibenzofuran from the product.