Electrically conductive elastomer foams were prepared by in situ vapor phase copolymerization of pyrrole and N‐methylpyrrole within preformed polyurethane foams. The conductive polymer is formed within the dense polymer phase of the foam, and the conductivity of the composite foam ranged from 10−1 to 10−7 S/cm. The conductvity depended on the density of the foam, the amount of conducting polymer incorporated, and the copolymer composition. Replacing with N‐methylpyrrole in the copolymer lowered the conductivity.
PPO ) have been determined. Tentative binary interaction energies were evaluated from mapping the copolymer composition miscibility boundaries using the Flory-Huggins theory combined with the binary interaction model. Data on phase-separation temperatures were too sparse for these systems to obtain refined estimates using the Sanchez-Lacombe theory. A negative interaction energy was obtained for the MA/AN pair; however, the MA unit showed strong repulsive interactions with all other monomer units examined here. 0 1994
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