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025ChemInform Abstract The results of potentiometry, cyclic voltammetry, chronoamperometry and chronopotentiometry (tungsten working electrode) show that the title system is quasi-reversible in the LiCl-KCl melt. The charge transfer rate constant is determined to be 1.5•10-3 cm/s and the diffusion coefficient of Sn2+ is 2.1•10-5 cm2/s. These results are confirmed by impedance measurements with a liquid tin electrode. The formation of Li-Sn alloys is observed at highly reducing potentials.