In this work, the numerical and experimental investigation of the cladding modes re-organization in high refractive index (HRI) coated Long Period Gratings (LPGs) is reported. Moreover, the effects of the cladding modes re-organization on the sensitivity to the surrounding medium refractive index (SRI) have been outlined. When azimuthally symmetric nano-scale HRI coatings are deposited along LPGs devices, a significant modification of the cladding modes distribution occurs, depending on the layer features (refractive index and thickness) and on the SRI. In particular, if layer parameters are properly chosen, the transition of the lowest order cladding mode into an overlay mode occurs. As a consequence, a cladding modes re-organization can be observed leading to relevant improvements in the SRI sensitivity in terms of wavelength shift and amplitude variations of the LPGs attenuation bands.

Chemical sensors are generally based on the integration of suitable sensitive layers and transducing mechanisms. Although inorganic porous materials can be effective, there is significant interest in the use of polymeric materials because of their easy fabrication process, lower costs and mechanical flexibility. However, porous polymeric absorbents are generally amorphous and hence present poor molecular selectivity and undesired changes of mechanical properties as a consequence of large analyte uptake. In this contribution the structure, properties and some possible applications of sensing polymeric films based on nanoporous crystalline phases, which exhibit all identical nanopores, will be reviewed. The main advantages of crystalline nanoporous polymeric materials with respect to their amorphous counterparts are, besides a higher selectivity, the ability to maintain their physical state as well as geometry, even after large guest uptake (up to 10–15 wt%), and the possibility to control guest diffusivity by controlling the orientation of the host polymeric crystalline phase. The final section of the review also describes the ability of suitable polymeric films to act as chirality sensors, i.e., to sense and memorize the presence of non-racemic volatile organic compounds.

In this work, the use of fiber long-period gratings (LPGs)—coated with nanoscale overlays of Syndiotactic Polystyrene (sPS) in the nanoporous crystalline δ form as specific and highly sensitive chemical sensors for in water monitoring—is proposed. The approach presented here, combines the excellent sorption properties of δ form sPS as a chemosensitive layer with the excellent refractive index sensitivity of LPG-based sensors as ideal transducers. In particular, when overlays with a high refractive index compared with the cladding one are deposited along the grating region, as in this case, the refraction-reflection regime at the cladding-overlay interface occurs. As result of this mechanism, the attenuation bands of coated LPGs would respond to the optical changes induced in the sensitive overlay due to chemical sorption by a significant modification of the peak central wavelength and intensity. The sensitivity depends strongly on the overlay thickness and the grating coupled cladding mode. Here, sensor probes were prepared by using a dip coating technique and a proprietary procedure to obtain the δ form sPS. An experimental demonstration of the sensor capability to perform sub-ppm detection of chloroform in water at room temperature is reported here. Also, the effects of the overlay thickness and the cladding mode order on sensor sensitivity and response time have been numerically and experimentally investigated.

We theoretically and experimentally investigated the reorganization of cladding modes in high-refractive-index- (HRI-) coated long-period gratings (LPGs), focusing on the influence of refractive-index sensitivity. When azimuthally symmetric nanoscale HRI coatings are deposited along LPG devices, a significant modification of the distribution of cladding modes occurs, depending on the layers' features (refractive index and thickness) and on the external refractive index. In particular, if these parameters are properly chosen, a transition between cladding modes and overlay modes occurs. Numerical and experimental effects of the mode transition on the sensitivity of the surrounding refractive index are described.

We report an original design approach based on the modal dispersion curves for the development of long period gratings in transition mode near the dispersion turning point exhibiting ultrahigh refractive index sensitivity. The theoretical model predicting a giant sensitivity of 9900 nm per refractive index unit in a watery environment was experimentally validated with a result of approximately 9100 nm per refractive index unit around an ambient index of 1.3469. This result places thin film coated LPGs as an alternative to other fiber-based technologies for high-performance chemical and biological sensing applications.