The study investigated the effects of post-blast explosive residues on ecosystems around Prodeco Quarry industry in Calabar Nigeria by collecting explosives residues and air/fumes samples. The variation between the intensity and temperature of explosive dissolution in the mine environment shows that TNT appears at the lowest temperature of 10 0 C and PETN reflected at about 35 0 C and NG shows almost at 58 0 C. Consequently, 5-15 kg of ANFO produced 10-30 lit/kg of nitrogen oxide compound (NOx) fumes while 20 kg ANFO produced 40 lit/kg of carbon monoxide fume. Also, 0.2 µg/L concentration of explosive in water recorded the highest mean recovery of 116.0 % while 1.0 µg/L recorded the highest values of 99.0 %. The mean recovery in soil sample is range between 105.0-126.0 % while that of forest is range between 91.0-107.0 % with the 50.0 µg/L concentration of explosive. The study concluded that the contaminating effects of the explosives residues have direct and indirect influences on the growth and development of the ecosystems.