Achieving
high current emission from one-dimensional nanowire (NW)
field emitters is essential for their application as X-ray sources.
In this study, field emission (FE) from tungsten trioxide NWs (WO3 NWs) was studied, and defects were found to be responsible
for the high electron emission current density. A high current density
of 13.75 mA/cm2 was achieved from large area, uniformly
patterned, and defect-rich monoclinic WO3 NWs, which were
grown directly on indium tin oxide (ITO) glass. Comparative investigations
were carried out on the field emission properties of individual NWs
with different defect concentrations. The results indicated that defect-related
electrical transport was the source of such high emission current.
This conclusion was further confirmed by a theoretical calculation
that considered both defect-related electrical transport and Joule
heating in the FE process. The conductivity induced by the defects
increases with rising temperature, and this mechanism regulated the
Joule heating during emission and helped to achieve high current density.
Furthermore, a flat panel X-ray source device using as-grown defect-rich
WO3 NWs as a cold cathode was fabricated and used to image
various objects. Clear X-ray images with a spatial resolution of approximately
25 μm were obtained.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.