We investigate the evaporation dynamics of a sessile droplet of
ethanol–water binary mixtures of different compositions laden
with alumina nanoparticles and compare with the no-loading condition
at different substrate temperatures. Shadowgraphy and infrared imaging
methods are used, and the experimental images are postprocessed using
a machine learning technique. We found that the loading and no-loading
cases display distinct wetting and contact angle dynamics. Although
the wetting diameter of a droplet decreases monotonically in the absence
of loading, the droplet with 0.6 wt % nanoparticle loading remains
pinned for the majority of its lifetime. The temporal variation of
the normalized droplet volume in the no-loading case has two distinct
slopes, with ethanol and water phases dominating the early and late
stages of evaporation, respectively. The normalized droplet volume
with 0.6 wt % loading displays a nearly linear behavior because of
the increase in the heat transfer rate. Our results from infrared
imaging reveal that a nanofluid droplet displays far richer thermal
patterns than a droplet without nanoparticle loading. In nanoparticle-laden
droplets, the pinning effect, as well as the resulting thermo-capillary
and thermo-solutal convection, causes more intense internal mixing
and a faster evaporation rate. Finally, a theoretical model is also
developed that satisfactorily predicts the evaporation dynamics of
binary nanofluid droplets.
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We experimentally investigate the evaporation of water−ethanol binary sessile droplets loaded with alumina nanoparticles on a critically inclined heated surface and compare it to the no-loading condition. In contrast to a droplet of pure fluids, several distinct and interesting phenomena observed in a binary-nanofluid droplet on a critically inclined substrate are reported for the first time. The critical angle at which a droplet begins to slide increases for ethanol-rich binary droplets up to 0.6 wt % nanoparticle loading. The critical angle for binary droplets also increases as the substrate temperature increases and as the ethanol concentration decreases for modest loading conditions. It is observed that the advancing side of a binary droplet is pinned in both the loading and no-loading scenarios, whereas the receding side is pinned in the loading case but shrinks continuously in the no-loading case. The pinning effect caused by nanoparticles results in a larger perimeter and surface area for the nanoparticle-laden droplets, enhancing the evaporation rates and significantly decreasing the lifetime of the nanoparticle-containing droplets compared to the no-loading case. Increasing the ethanol percentage in the binary droplet placed on an inclined substrate produces complex thermosolutal Marangoni convection, which becomes more affluent in the case of nanoparticles loading than the no-loading condition. The radial symmetry of the circular coffee ring structure observed on a horizontal surface is shattered in the inclined case because the droplet elongates and preferentially deposits toward the advancing side of the triple line due to the action of the body force. Despite its fundamental nature, the present study can contribute to understanding many practical applications.
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