A modeling and simulation study, along with an economic analysis, was carried out for the separation of cyanide from industrial wastewater using a flat sheet cross‐flow nanofiltration membrane module. With the addition of a pre‐microfiltration step, nanofiltration was carried out using real coke wastewater under different operating conditions. Under the optimum operating pressure of 13 bars and a pH of 10.0, a rate of more than 95% separation of cyanide was achieved. That model predictions agreed very well with the experimental findings, as is evident in the Willmott d‐index value (>0.95) and relative error (<0.1). Studies were carried out with industrial wastewater instead of a synthetic solution, and an economic analysis was also done, considering the capacity of a running coking plant. The findings are likely to be very useful in the scale‐up and design of industrial plants for the treatment of cyanide‐bearing wastewater.
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