One of the unsolved
problems of dynamics in supercooled liquids
are the differences in spectral shape of the structural relaxation
observed among different methods and substances, and a possible generic
line shape has long been debated. We show that the light scattering
spectra of very different systems, e.g., hydrogen bonding, van der
Waals liquids, and ionic systems, almost perfectly superimpose and
show a generic line shape of the structural relaxation, following
∝ ω–1/2 at high frequencies. In dielectric
spectra the generic behavior is recovered only for systems with low
dipole moment, while in strongly dipolar liquids additional cross-correlation
contributions mask the generic structural relaxation.
We suggest a way to disentangle self- from cross-correlations in the dynamic susceptibility of the glass former glycerol by combining dielectric relaxation (BDS) with light scattering (DDLS), field cycling NMR, and shear compliance (SC) data.
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