There is strong experimental evidence that the superconductor Sr2RuO4 has a chiral p-wave order parameter. This symmetry does not require that the associated gap has nodes, yet specific heat, ultrasound and thermal conductivity measurements indicate the presence of nodes in the superconducting gap structure of Sr2RuO4. Theoretical scenarios have been proposed to account for the existence of deep minima or accidental nodes (minima tuned to zero or below by material parameters) within a p-wave state. Other scenarios propose chiral d-wave and f -wave states, with horizontal and vertical line nodes, respectively. To elucidate the nodal structure of the gap, it is essential to know whether the lines of nodes (or minima) are vertical (parallel to the tetragonal c axis) or horizontal (perpendicular to the c axis). Here, we report thermal conductivity measurements on single crystals of Sr2RuO4 down to 50 mK for currents parallel and perpendicular to the c axis. We find that there is substantial quasiparticle transport in the T = 0 limit for both current directions. A magnetic field H immediately excites quasiparticles with velocities both in the basal plane and in the c direction. Our data down to Tc/30 and down to Hc2/100 show no evidence that the nodes are in fact deep minima. Relative to the normal state, the thermal conductivity of the superconducting state is found to be very similar for the two current directions, from H = 0 to H = Hc2. These findings show that the gap structure of Sr2RuO4 consists of vertical line nodes. This rules out a chiral d-wave state. Given that the c-axis dispersion (warping) of the Fermi surface in Sr2RuO4 varies strongly from surface to surface, the small a − c anisotropy suggests that the line nodes are present on all three sheets of the Fermi surface. If imposed by symmetry, vertical line nodes would be inconsistent with a p-wave order parameter for Sr2RuO4. To reconcile the gap structure revealed by our data with a p-wave state, a mechanism must be found that produces accidental line nodes in Sr2RuO4.
The thermal conductivity κ of the iron-based superconductor FeSe was measured at temperatures down to 75 mK in magnetic fields up to 17 T. In a zero magnetic field, the electronic residual linear term in the T=0 K limit, κ_{0}/T, is vanishingly small. The application of a magnetic field B causes an exponential increase in κ_{0}/T initially. Those two observations show that there are no zero-energy quasiparticles that carry heat and therefore no nodes in the superconducting gap of FeSe. The full field dependence of κ_{0}/T has the classic two-step shape of a two-band superconductor: a first rise at very low field, with a characteristic field B^{⋆}≪B_{c2}, and then a second rise up to the upper critical field B_{c2}. This shows that the superconducting gap is very small (but finite) on one of the pockets in the Fermi surface of FeSe. We estimate that the minimum value of the gap, Δ_{min}, is an order of magnitude smaller than the maximum value, Δ_{max}.
The thermal conductivity κ of the cuprate superconductor La1.6−xNd0.4SrxCuO4 was measured down to 50 mK in seven crystals with doping from p = 0.12 to p = 0.24, both in the superconducting state and in the magnetic field-induced normal state. We obtain the electronic residual linear term κ0/T as T → 0 across the pseudogap critical point p = 0.23. In the normal state, we observe an abrupt drop in κ0/T upon crossing below p , consistent with a drop in carrier density n from 1+p to p, the signature of the pseudogap phase inferred from the Hall coefficient. A similar drop in κ0/T is observed at H = 0, showing that the pseudogap critical point and its signatures are unaffected by the magnetic field. In the normal state, the Wiedemann-Franz law, κ0/T = L0/ρ(0), is obeyed at all dopings, including at the critical point where the electrical resistivity ρ(T ) is T -linear down to T → 0. We conclude that the non-superconducting ground state of the pseudogap phase at T = 0 is a metal whose fermionic excitations carry heat and charge as conventional electrons do.
The thermal conductivity κ of the quasi-2D organic spin-liquid candidate EtMe3Sb[Pd(dmit)2]2 (dmit-131) was measured at low temperatures, down to 0.07 K. We observe a vanishingly small residual linear term κ0/T , in κ/T vs T as T → 0. This shows that the low-energy excitations responsible for the sizeable residual linear term γ in the specific heat C, seen in C/T vs T as T → 0, are localized. We conclude that there are no mobile gapless excitations in this spin liquid candidate, in contrast with a prior study of dmit-131 that reported a large κ0/T value [Yamashita et al., Science 328, 1246(2010]. Our study shows that dmit-131 is in fact similar to κ-(BEDT-TTF)2Cu2(CN)3, another quasi-2D organic spin-liquid candidate where a vanishingly small κ0/T and a sizeable γ are seen. We attribute heat conduction in these organic insulators without magnetic order to phonons undergoing strong spin-phonon scattering, as observed in several other spin-liquid materials. arXiv:1904.10402v3 [cond-mat.str-el]
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