Optical properties of natural or designed materials are determined by the electromagnetic multipole moments that light can excite in the constituent particles. In this paper, we present an approach to calculating the multipole excitations in arbitrary arrays of nanoscatterers in a dielectric host medium. We introduce a simple and illustrative multipole decomposition of the electric currents excited in the scatterers and connect this decomposition to the classical multipole expansion of the scattered field. In particular, we find that completely different multipoles can produce identical scattered fields. The presented multipole theory can be used as a basis for the design and characterization of optical nanomaterials.

In general, optical nanomaterials composed of noncentrosymmetric nanoscatterers are bifacial, meaning that two counter-propagating waves inside the material behave differently. Thus far a practical theory for the description of such materials has been missing. Herein, we present a theory that connects the design of the bifacial nanomaterial's "atoms" with the refractive index and wave impedance of the medium. We also introduce generalized Fresnel coefficients and investigate the role of electromagnetic multipoles on the bifaciality. We find that in any material two counter-propagating waves must experience the same refractive index, but their impedances can differ. The model is demonstrated in practice by the design of a nanomaterial slab with one of its facets being optically reflective, while the other being totally non-reflective.

We introduce a simple theoretical model that describes the interaction of light with optical metamaterials in terms of interfering optical plane waves. In this model, a metamaterial is considered to consist of planar arrays of densely packed nanoparticles. In the analysis, each such array reduces to an infinitely thin homogeneous sheet. The transmission and reflection coefficients of this sheet are found to be equal to those of an isolated nanoparticle array and, therefore, they are easy to evaluate numerically for arbitrary shapes and arrangements of the particles. The presented theory enables fast calculation of electromagnetic fields interacting with a metamaterial slab of an arbitrary size, which, for example, can be used to retrieve the effective refractive index and wave impedance in the material. The model is also shown to accurately describe optically anisotropic metamaterials that in addition exhibit strong spatial dispersion, such as bifacial metamaterials.

In subwavelength-sized particles, light-induced multipole moments of orders higher than the electric dipole are usually negligibly small, which allows for the light-matter interaction to be accurately treated within the electric dipole approximation. In this work we show that in a specially designed meta-atom, a disc metadimer, the electric quadrupole and magnetic dipole can be the only excitable multipoles. This condition is achieved in a narrow but tunable spectral range of visible light both for individual metadimers and for a periodic array of such particles. The electromagnetic fields scattered by the metadimers fundamentally differ from those created by electric dipoles. A metamaterial composed of such metadimers will therefore exhibit unusual optical properties.

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