Understanding solute mixing within real vegetation is critical to predicting and evaluating the performance of engineered natural systems such as storm water ponds. For the first time, mixing has been quantified through simultaneous laboratory measurements of transverse and longitudinal dispersion within artificial and real emergent vegetation. Dispersion coefficients derived from a routing solution to the 2‐D Advection Dispersion Equation (ADE) are presented that compare the effects of vegetation type (artificial, Typha latifolia or Carex acutiformis) and growth season (winter or summer). The new experimental dispersion coefficients are plotted with the experimental values from other studies and used to review existing mixing models for emergent vegetation. The existing mixing models fail to predict the observed mixing within natural vegetation, particularly for transverse dispersion, reflecting the complexity of processes associated with the heterogeneous nature of real vegetation. Observed stem diameter distributions are utilized to highlight the sensitivity of existing models to this key length‐scale descriptor, leading to a recommendation that future models intended for application to real vegetation should be based on probabilistic descriptions of both stem diameters and stem spacings.

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ReuseUnless indicated otherwise, fulltext items are protected by copyright with all rights reserved. The copyright exception in section 29 of the Copyright, Designs and Patents Act 1988 allows the making of a single copy solely for the purpose of non-commercial research or private study within the limits of fair dealing. The publisher or other rights-holder may allow further reproduction and re-use of this version -refer to the White Rose Research Online record for this item. Where records identify the publisher as the copyright holder, users can verify any specific terms of use on the publisher's website. TakedownIf you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing eprints@whiterose.ac.uk including the URL of the record and the reason for the withdrawal request.Development of a laboratory system and 2D routing analysis to determine solute mixing within aquatic vegetation Patrick West, James Hart, Ian Guymer, and Virginia Stovin 1 Abstract A laser induced fluorometry (LIF) system was developed to quantify mixing within spatially variable aquatic vegetation. A comparison is made between intrusive fluorometry techniques and the application of LIF, to quantify mixing in real vegetation in the laboratory setting. LIF provides greater spatial resolution when compared to point fluorometry. Furthermore, LIF is non-intrusive. A twodimensional routing procedure is used to calculate the longitudinal and transverse velocities and mixing coefficients from a single pulse injection of tracer within a vegetated patch.