International audienceTexture characterization of photographic prints can provide scholars with valuable information regarding photographers? aesthetic intentions and working practices. Currently, texture assessment is strictly based on the visual acuity of a range of scholars associated with collecting institutions, such as museum curators and conservators. Natural interindividual discrepancies, intraindividual variability, and the large size of collections present a pressing need for computerized and automated solutions for the texture characterization and classification of photographic prints. In the this article, this challenging image processing task is addressed using an anisotropic multiscale representation of texture, the hyperbolic wavelet transform (HWT), from which robust multiscale features are constructed. Cepstral distances aimed at ensuring balanced multiscale contributions are computed between pairs of images. The resulting large-size affinity matrix is then clustered using spectral clustering, followed by a Ward linkage procedure. For proof of concept, these procedures are first applied to a reference data set of historic photographic papers that combine several levels of similarity and second to a large data set of culturally valuable photographic prints held by the Museum of Modern Art in New York. The characterization and clustering results are interpreted in collaboration with art scholars with an aim toward developing new modes of art historical research and humanities-based collaboration

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Laser desorption mass spectroscopy has been used to characterize both modern and ∼ 150-year-old daguerreotypes. Such investigations are a necessary prelude to attempts to clean them of tarnish and other contaminants by laser ablation of the surface layers. Both positive- and negative-ion time-of-flight spectra were obtained following YAG laser ablation/desorption at 1064, 532, and 355 nm. Major peaks obtained from several daguerreotypes reveal expected elements from the substrate (Ag, Cu) as well as the developing (Hg) and gilding (Au) processes. Silver clusters (Agn) may reflect surface desorption of molecules or, alternatively, aggregates formed in the ejection process. Silver sulfide molecules observed from old daguerreotypes are the signature of the tarnishing process.