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The effect of clay loading on the mechanical behavior and melt state linear viscoelastic properties of intercalated polycarbonate (PC) nanocomposites was investigated. At low frequencies, the linear dynamic oscillatory moduli data revealed diminished frequency dependence with increasing nanoclay loading. The 3.5 and 5 wt% clay nanocomposites exhibited dramatically altered relaxation behavior, from liquid‐like to pseudo‐solid–like, compared to the pure PC and the 1.5 wt% clay nanocomposite. Thermal degradation of PC resulted from the melt compounding of organo‐modified nanoclays was evident from the reduction in the glass transition temperature and molecular weight of the PC nanocomposites. These nanocomposites also exhibited a significant decrease in the extent of tensile elongation and ductility with respect to the nanoclay incorporation. A concomitant decrease in the rheological properties at high frequencies was also observed, and was consistent with the lowering of the molecular weight of PC, particularly near or above the percolation threshold of nanoclay. These nanocomposites, nevertheless, exhibited elastic‐plastic deformation in compression, regardless of nanoclay content. Polym. Eng. Sci. 44:825–837, 2004. © 2004 Society of Plastics Engineers.

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The procedure for determining quasi-static fracture toughness of ceramics has been standardized. To expand the loading rate into the dynamic region, the dynamic equilibrium over the entire specimen needs to be satisfied to interpret the crack tip loading state with the far-field loading conditions. Furthermore, to determine the loading-rate effects, the loading rate at the crack tip should be nearly constant during an experiment. A new fourpoint bending experimental technique, based on a split Hopkinson pressure bar, has been developed to determine the dynamic fracture toughness of ceramics at high rates under valid conditions, which is demonstrated through the determination of the dynamic fracture toughness as a function of loading rate for a silicon carbide (SiC-N).

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