N -methyl-2-pyrrolidone (NMP) is the most common solvent for manufacturing cathode electrodes in the battery industry; however, it is becoming restricted in several countries due to its negative environmental impact. Taking into account that ∼99% of the solvent used during electrode fabrication is recovered, dimethylformamide (DMF) is a considerable candidate to replace NMP. The lower boiling point and higher ignition temperature of DMF lead to a significant reduction in the energy consumption needed for drying the electrodes and improve the safety of the production process. Additionally, the lower surface tension and viscosity of DMF enable improved current collector wetting and higher concentrations of the solid material in the cathode slurry. To verify the suitability of DMF as a replacement for NMP, we utilized screen printing, a fabrication method that provides roll-to-roll compatibility while allowing controlled deposition and creation of sophisticated patterns. The battery systems utilized NMC (LiNi x Mn y Co z O 2 ) chemistry in two configurations: NMC523 and NMC88. The first, well-established NCM523, was used as a reference, while NMC88 was used to demonstrate the potential of the proposed method with high-capacity materials. The cathodes were used to create coin and pouch cell batteries that were cycled 1000 times. The achieved results indicate that DMF can successfully replace NMP in the NMC cathode fabrication process without compromising battery performance. Specifically, both the NMP blade-coated and DMF screen-printed batteries retained 87 and 90% of their capacity after 1000 (1C/1C) cycles for NMC523 and NMC88, respectively. The modeling results of the drying process indicate that utilizing a low-boiling-point solvent (DMF) instead of NMP can reduce the drying energy consumption fourfold, resulting in a more environmentally friendly battery production process.
Memristors have attracted significant interest in recent years because of their role as a missing electronic component and unique functionality that has not previously existed. Since the first discoveries of the existence of memristive materials, various different fabrication processes for memristors have been presented. Here, a simple additive fabrication process is demonstrated where memristors were deposited on a polymer substrate by conventional inkjet printing. The memristor structure was printed on a 125 μm thick polyethylene terephthalate (PET) substrate by sandwiching a thin layer of TiO x between two silver nanoparticle ink electrodes. Current-voltage (IV) characterization measurements were performed and they showed clear memristive behavior when voltage pulse amplitude varied between −1.5 V and 1.5 V. The corresponding resistance change is approximately between 150 Ω and 75 kΩ. In order to demonstrate the switching scheme in practical application, printed memristors and a printed voltage doubler were connected with a piezoelectric element. The element was subjected to impact-type excitation thus producing an electric charge that was able to switch the memristor between high and low resistive states. These results pave the way for an exploitation of cost-efficient, self-sufficient, all-printable memory elements for wide utilization in future electronics applications.
The point-of-care testing (POCT) is having increasing role on modern health care systems due to a possibility to perform tests for patients conveniently and immediately. POCT includes lot of disposable devices because of the environment they are often used. For a disposable system to be reasonably utilized, it needs to be high in quality but low in price. Optics based POCT systems are interesting approach to be developed, and here we describe a low-cost fabrication process for microlens arrays for microscopy. Lens arrays having average lens diameter of 222 μm with 300 μm lens pitch were fabricated. The lenses were characterized to have standard deviation of 0.06 μm in height and 4.61 μm in diameter. The resolution limit of 3.9μm is demonstrated with real images, and the images were compared with ones made with glass and polycarbonate lens arrays. The image quality is at the same level than with the glass lenses and the manufacturing costs are very low, thus making them suitable for POCT applications.
The production methods of Li-ion batteries need to be adapted for the goals of a more sustainable future. This research focuses on replacing toxic NMP with less harmful solvents, without compromising the batteries' performance. From the perspective of printed electronics, the replacement is especially desirable because the aggressiveness of NMP has a negative impact on various components of printers. In this research, the novel NCM88 material has been used to fabricate the cathode layers of Li-ion batteries. Two fabrication methods (blade coating and screen printing) and two different slurry/ink formulations (NMP-and DMF-based) have been analysed. For the purpose of physicochemical and electrical characterization, the fabricated cathodes were used to assemble pouch cells and half-cells with metallic lithium as counter electrode. Results indicate that screen-printed cathodes fabricated with DMFbased slurries perform similarly to those fabricated through blade-coating NMP slurries.
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