The research paper presents the impact of the scandium additive and various conditions of the heat treatment on copper mechanical, electrical and heat resistance properties. The performed research works included manufacturing of CuSc0.15 and CuSc0.3 alloys through metallurgical synthesis with the use of induction furnace and following crystallization in graphite crucibles at ambient temperature. Additionally, a CuZr0.15 alloy was produced as a reference material for previously synthesized Cu-Sc alloys. During research, the selection of heat treatment for the produced materials was conducted in order to obtain the highest mechanical-electrical properties ratio. Materials obtained in such a way were next subjected to thermal resistance tests. Parameters of thermal resistance test included temperatures from the range of 200-700 °C and 1 h of annealing time. The research has shown that CuSc0.15 and CuSc0.3 alloys have higher heat resistance after their precipitation hardening compared to the Cu-Zr alloy. The paper also presents microstructural research of the produced materials, which showed that alloying elements precipitates are mainly localized at the grain boundaries of the material structure.
The properties of copper in its solid state are strongly affected by the crystallization conditions of the liquid material. ETP grade copper (Electrolytic Tough Pitch Copper) contains oxygen, which causes Cu2O oxide to crystallize in the interdendritic spaces during solidification process which due to the shape of continuous casting mould and the feed of liquid copper during the crystallization process in strand casting might cause a high risk of macrosegregation of oxygen in the copper structure. In the current paper the implied interactions of the dendritic structure of the copper strand in terms of homogeneity at the cross-section of its electrical, mechanical and plastic properties determined based on the samples taken parallelly and perpendicularly to the surface of the dendritic boundaries were analysed. The obtained results were confronted with scanning electron microscopy (SEM) images of the fractures formed during uniaxial tensile test. It has been observed that when the crystallites were arranged perpendicularly to the tensile direction the yield strength (YS) was lower and the fractures were brittle. On the other hand, when the crystallites were arranged parallelly to the tensile direction the fractures were plastic and elongated necking was observed along with the higher YS and total elongation values. The differences in values vary in terms of the applied direction of the tensile force. A characteristic positioning of the Cu2O oxide particles inside the fracture depending on the crystallite alignment and the direction of the applied tensile force has been observed.
Continuous pressure put on researchers all over the world these days to design materials of improved properties create opportunities to study new methods of production in conjunction with entirely new and innovative materials such as alloys or composites. The authors in the current research manufactured aluminium reinforced with glass fibre (GF) using metallurgical synthesis, which is an unconventional and not sufficiently studied method of production. The composites with 1, 2 and 5 wt.% of glass fibre were produced with additional material obtained using consolidation of aluminium powder in extrusion process as reference material with 5 wt.% of glass fibre. All the materials were subjected to series of tests in order to determine their microstructure, density, electrical properties, hardness and susceptibility to plastic working in the compression test. It was found that glass fibre during metallurgical synthesis of aluminium composite partially melted and thus did not reinforce the material as well as during extrusion, which has been observed not only in the scanning electron microscope (SEM) and energy-dispersive X-ray (EDX) analysis but also in the analysis of macroscopic physical and mechanical properties. Based on the analysed samples, it may be stated that electrical conductivity of the samples obtained via metallurgical synthesis is higher than might be estimated on the basis of the rule of mixtures and glass fibre content and concerning the sample with 5 wt.% of GF is higher (32.1 MS/m) than of the reference material obtained in extrusion process (30.6 MS/m). Similar situation has been observed in terms of hardness of the tested samples where a minor increase in hardness was noticeable as the amount of glass fibre increased in the composites obtained by metallurgical synthesis. It is believed to be related to the melting of glass fibre, which reduced the volume fraction of GF containing mainly silicon oxides and their diffusion into the aluminium matrix, thus causing solid solution strengthening.
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