This study focuses on the causes, modalities and obstacles of sediment transfer in the longest cell of littoral sand drift documented on Earth so far. Sand derived from the Orange River is dragged by swell waves and persistent southerly winds to accumulate in four successive dunefields in coastal Namibia to Angola. All four dunefields are terminated by river valleys, where aeolian sand is flushed back to the ocean; and yet sediment transport continues at sea, tracing an 1800 km long submarine sand highway. Sand drift would extend northward to beyond the Congo if the shelf did not become progressively narrower in southern Angola, where drifting sand is funnelled towards oceanic depths via canyon heads connected to river mouths. Garnet–magnetite placers are widespread along this coastal stretch, indicating systematic loss of the low‐density feldspatho‐quartzose fraction to the deep ocean. More than half of Moçamedes Desert sand is derived from the Orange River, and the rest in similar proportions from the Cunene River and from the Swakop and other rivers draining the Damara Orogen in Namibia. The Orange fingerprint, characterized by basaltic rock fragments, clinopyroxene grains and bimodal zircon‐age spectra with peaks at ca 0·5 Ga and ca 1·0 Ga, is lost abruptly at Namibe, and beach sands further north have abundant feldspar, amphibole‐epidote suites and unimodal zircon‐age spectra with a peak at ca 2·0 Ga, documenting local provenance from Palaeoproterozoic basement. Along with this oblique‐rifted continental margin, beach placers are dominated by Fe–Ti–Cr oxides with more monazite than garnet and thus have a geochemical signature sharply different from beach placers found all the way along the Orange littoral cell. High‐resolution mineralogical studies allow us to trace sediment dispersal over distances of thousands of kilometres, providing essential information for the correct reconstruction of ‘source to sink’ relationships in hydrocarbon exploration and to predict the long‐term impact of man‐made infrastructures on coastal sediment budgets.
Despite the influence of other geological and geomorphological factors, 20 chemical weathering at the Earth's surface is strongly controlled by climate. Thus, a 21 measure of weathering intensity determined from soils or sediments should provide information about the climatic conditions associated with their formation. Available 23 geochemical and mineralogical data on modern fluvial and marine muds from different 24 regions of southern Africa and its Atlantic continental margin are used to review the 25 links between sediment composition and climatic properties together with the 26 possible causes of variance. Although river muds may not be generated exclusively in a 27 single sedimentary cycle and erosion and weathering processes do not necessarily take 28 place in a spatially homogeneous way, significant relationships between mineralogical 29 and geochemical signatures of river mud and rainfall in the corresponding catchment 30 area were recognised. Our study shows that the composition of clay is strongly 31 influenced by climatically-driven weathering, whilst coarser mud fractions tend to be 32 more affected by provenance, grain size, hydraulic sorting, and recycling. In the marine 33 environment the climatic signal may be lost even in clay, because of hydraulic 34 fractionation, authigenic mineral growth and mixing with foreign particles. Given the 35 ubiquitous character of fluvial muds, and the easy and non-expensive methods 36 available for separating and analysing clay fractions, their geochemical fingerprints 37 represent a most precious source of information concerning climate. Any geochemical 38 parameter used as a regional proxy of climate, however, still requires that the diversity 39 of geological, geomorphological, and biological factors that affect its value are 40 cautiously considered.
In the modern era, due to the rapid increase in urbanization and industrialization in the vicinity of the Himalayas, heavy metals contamination in soil has become a key priority for researchers working globally; however, evaluation of the human and ecological risks mainly in hilly areas remains limited. In this study, we analyzed indices like the contamination factor (CF), degree of contamination (DC), enrichment factor (EF), geochemical index (Igeo), pollution ecological risk index (PERI), and pollution load index (PLI), along with cancer risk (CR) and hazard indices (HI), to ascertain the eco-environmental and human risks of using heavy metals in datasets collected from 168 sampling locations in Uttarakhand, India. The evaluation calculated of Igeo, EF, and CF suggests that represented soil samples were moderately contaminated and highly augmented with Rb, while PERI (75.56) advocates a low ecological risk. Further, PLI and DC (PLI: 1.26; DC: 36.66) show a possible health risk for the native population in the vicinity of the studied catchment. The hazard index (HI) is estimated greater than 1 (HI > 1) for Cr and Mn, representing a possible risk for cancer. However, adults are free from cancer risk, and other studied elements have been reported as noncarcinogenic. This assessment gives important information to policymakers, environmentalists, and foresters for taking mitigation measures in advance to mitigate the potential future risk of soil pollution on humans, ecology, and the environment.
A never solved problem in sedimentary petrology is the origin of sandstone consisting exclusively of quartz and most durable heavy minerals. The Congo River offers an excellent test case to investigate under which tectonic, geomorphological, climatic, and geochemical conditions pure quartzose sand is generated today. In both upper and lowermost parts of the catchment, tributaries contain significant amounts of feldspars, rock fragments, or moderately stable heavy minerals pointing at the central basin as the main location of the "quartz factory". In Congo sand, quartz is enriched relatively to all other minerals including zircon, as indicated by Si/Zr ratios much higher than in the upper continental crust. Selective elimination of old zircons that accumulated radiation damage through time is suggested by low percentages of grains yielding Archean U-Pb ages despite the basin being surrounded by Archean cratonic blocks. Intense weathering is documented by the lack of carbonate grains in sand and by dominant kaolinite and geochemical signatures in mud. In sand, composed almost entirely of SiO 2 , the weathering effect is masked by massive addition of quartz grains recycled during multiple events of basin inversion since the Proterozoic.Changes in mineralogical, geochemical, and geochronological signatures across Bas-Congo concur to suggest that approximately 10% of the sand supplied to the Atlantic Ocean is generated by rapid fluvial incision into the recently uplifted Atlantic Rise. The Congo River connects with a huge canyon ~ 30 km upstream of the mouth, and pure quartzose sand is thus funnelled directly toward the deep-sea to feed a huge turbidite fan. Offshore sediments on both sides of the canyon are not derived from the Congo River. They reflect mixed provenance, including illite-rich dust windblown from the arid Sahel and augite, hypersthene, and smectite ejected from volcanic centres probably situated along the Cameroon Line in the north.Because mixing of detritus from diverse sources and supply of polycyclic grains almost invariably occurs in the terminal lowland tract of a sediment-routing-system, no ancient sandstone can be safely considered as entirely first-cycle. Moreover, the abundance of pure quartzarenite in the rock record can hardly be explained by chemical weathering or physical recycling alone. The final cleansing of minerals other than quartz, zircon, tourmaline, and rutile requires one or more cycles of chemical dissolution during diagenesis, which operates at higher temperatures and over longer periods than weathering at the Earth's surface.
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