Biomass is a renewable energy source that, due to its strong seasonality, needs to be stored, handled, and managed under suitable conditions for its optimal use. Storage is therefore a key process in which biomass can lose many of its qualities as a fuel, but which can also serve to improve the condition of the resource. This paper presents results from a study to assess the effect of large‐scale storage on a range of different biomass resources that was carried out at an electricity generation plant located in southern Spain. It included a series of field tests carried out with different types of biomass resources, to observe the behavior of these products during storage and the changes in their main characteristics. Based on these results, recommendations have been proposed for the optimal storage management of each of the products. The testing program confirms that the initial moisture content of the biomass, particle size, and the leafy content are critical aspects to consider to avoid self‐ignition and dry matter losses. Biomass with high moisture content should therefore be stored in small stockpiles and should be consumed immediately. This is especially important in the case of olive leaves and pine prunings when they have a high initial moisture content. Stockpiles of drier biomass, such as dried olive pomace, fruit tree pruning or dried olive pruning can reach up to 1200 t and be stored for up to 6 months, under adequately controlled conditions. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd