Carbon nanotubes (CNTs) and boron nitride nanotubes (BNNTs) are one-dimensional materials with high thermal conductivity and similar crystal structures. Additionally, BNNTs feature higher thermal stability in air than CNTs. In this work, a single-walled carbon nanotube (SWCNT) film was used as a template to synthesize a BNNT coating by the chemical vapor deposition (CVD) method to form a coaxial heterostructure. Then, a contact-free steady-state infrared (IR) method was adopted to measure the in-plane sheet thermal conductance of the as-synthesized film. The heterostructured SWCNT− BNNT film demonstrates an enhanced sheet thermal conductance compared with the bare SWCNT film. The increase in sheet thermal conductance shows a reverse relationship with SWCNT film transparency. An enhancement of over 80% (from ∼3.6 to ∼6.4 μW•K −1 •sq −1 ) is attained when the BNNT coating is applied to an SWCNT film with a transparency of 87%. This increase is achieved by BNNTs serving as an additional thermal conducting path. The relationship between the thermal conductance increase and transparency of the SWCNT film is studied by a structured modeling of the SWCNT film. We also discuss the effect of annealing on the thermal conductance of SWCNTs before BNNT growth. Along with the preservation of high electrical conductance, the enhanced thermal conductance of the heterostructured SWCNT−BNNT films makes them a promising building block for thermal and optoelectronic applications. KEYWORDS: single-walled carbon nanotube film, boron nitride nanotube, van der Waals heterostructure, in-plane sheet thermal conductance, chemical vapor deposition, infrared thermography

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The thermal properties of individual single-walled carbon nanotubes (SWCNTs) have been well documented in the literature following decades of intensive study. However, when SWCNTs form a macroscale assembly, the thermal transport in these complex structures usually not only depends on the properties of the individual tubes, but also is affected and sometimes dominated by inner structural details, e.g. bundles and junctions. In this work, we first performed an experimental measurement of the thermal conductivities of individual SWCNT bundles of different sizes using a suspended micro-thermometer. The results, together with the data that we obtained from a previous work, give a complete experimental understanding of the effect of bundling on the thermal conductivity of SWCNTs. With these quantitative understandings, we propose a phenomenological model to describe the thermal transport in two-dimensional (2D) SWCNT films. The term ‘line density’ is defined to describe the effective thermal transport channels in this complex 2D network. Along with experimentally obtained geometric statistics and film transparency, the thermal conductance of SWCNTs is estimated, and the effects of bundle length, diameter, and contact conductance are systematically discussed. Finally, we extend this model to explain thermal transport in 2D networks of one-dimensional van der Waals heterostructures, which are coaxial hetero-nanotubes we recently synthesized using SWCNTs as the template. This extended model suggests that the contribution of boron nitride nanotubes (BNNTs) to the overall performance of a SWCNT–BNNT heterostructured film depends on the transparency of the original SWCNT film. The increase in the thermal conductance of a highly transparent film is estimated to be larger than that of a less transparent film, which shows a good agreement with our experimental observations and proves the validity of the proposed phenomenological model.

A utility piezoelectric energy harvester with low frequency and high-output voltage: Theoretical model, experimental verification and energy storage AIP Advances 6, 095208 (2016); https://doi.org/10.1063/1.4962979 Piezoelectric energy harvesting: State-of-the-art and challenges Applied Physics Reviews 1, 031104 (2014); https://doi.org/10.1063/1.4896166 AIP ADVANCES 6, 055002 (2016) Performance of pre-deformed flexible piezoelectric cantilever in energy harvesting This paper proposes a novel structure for pre-rolled flexible piezoelectric cantilevers that use wind energy to power a submunition electrical device. Owing to the particular installation position and working environment, the submunition piezoelectric cantilever should be rolled when not working, but this pre-rolled state can alter the energy harvesting performance. Herein, a working principle and installation method for piezoelectric cantilevers used in submunitions are introduced. To study the influence of the pre-rolled state, pre-rolled piezoelectric cantilevers of different sizes were fabricated and their performances were studied using finite element analysis simulations and experiments. The simulation results show that the resonance frequency and stiffness of the pre-rolled structure is higher than that of a flat structure. Results show that, (1) for both the pre-rolled and flat cantilever, the peak voltage will increase with the wind speed. (2) The pre-rolled cantilever has a higher critical wind speed than the flat cantilever. (3) For identical wind speeds and cantilever sizes, the peak voltage of the flat cantilever (45 V) is less than that of the pre-rolled cantilever (56 V). (4) Using a full-bridge rectifier, the output of the pre-rolled cantilever can sufficiently supply a 10 µF capacitor, whose output voltage may be up to 23 V after 10 s. These results demonstrate that the pre-rolled piezoelectric cantilever and its installation position used in this work are more suitable for submunition, and its output sufficiently meets submunition requirements. C 2016 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license