This article deals with thermal properties of selected biodiesel and bioethanol samples (biodiesel No 1, No 2 and bioethanol No 1, No 2). Biodiesel is renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant grease for use in diesel vehicles. Biodiesel‘s physical properties are similar to those of petroleum diesel, but it is a cleaner-burning alternative fuel. Ethanol (CH3CH2OH) is a clear liquid. Also known as ethyl alcohol, grain alcohol, and EtOH, the molecules in this fuel contain a hydroxyl group (OH-) bonded to a carbon atom. Ethanol is made of the same chemical compound regardless of whether it is produced from starch and sugar-based feedstocks, such as corn grain, sugar cane, etc. The hot wire method was used for thermal parameters measurements. The experiment is based on measuring the temperature rise vs. time evaluation of an electrically heated wire embedded in the tested material. Thermal conductivity is derived from the resulting change in temperature over a known time interval. For two samples of biodiesel and two samples of bioethanol, there were determined basic thermophysical parameters - thermal conductivity and thermal diffusivity. Two series of measurements were made for each sample of biodiesel and bioethanol. In the first series, there were measured the thermal conductivity and thermal diffusivity at constant room temperature 20 °C. Every thermophysical parameter was measured 10 times for each sample. The results were statistically processed. In the second series of measurements, there were measured the relations of thermal conductivity and thermal diffusivity to temperature in temperature range 20-29 °C. It was evident from results that all measured dependencies are nonlinear. Polynomial functions described by polynomial coefficients were obtained for both thermophysical parameters. The type of function was selected according to statistical evaluation based on the coefficient of determination for every thermophysical parameter graphical dependency. All obtained results are presented in Figures 1-4 and in Tables 1-4. The results of thermophysical parameters measurements of biodiesel and bioethanol could be compared with the values presented in literature.
Presented paper is focused on comparison of certain physical properties of selected vegetable oils. Physical properties, such as density, dynamic, kinematic viscosity and fluidity, were experimentally determined. All experiments were conducted on two samples of vegetable oils: sunflower and extra virgin olive oils with approximate temperature range of 5–32 °C. Density of oils was determined by oscillation method utilizing digital densimeter Anton Paar DMA 4500M at different temperatures. Dynamic viscosity was measured by means of rotational viscometer Anton Paar DV-3P. The rest of rheological parameters were determined on the basis of their definitions. Obtained results are depicted as graphical dependencies of rheological parameters and density on temperature. These dependencies of vegetable oils on dynamic and kinematic viscosity showed decreasing exponential shape, which is in compliance with Arrhenius equation; temperature dependencies on fluidity showed an increasing exponential shape for both samples. Density dependencies of samples on temperature were characteristic with decreasing linear function within measured temperature range. Similar results were achieved by other researchers. On the basis of measured values, it is evident that dynamic viscosity of extra virgin olive oil shows higher values than sunflower oil viscosity, which is a result of different composition of oils.
This article deals with thermal properties of selected biooils (Plahyd S -biooil No1 and Plahyd N -biooil No2) and rheologic properties of rapeseed oil. Plahyd S is a synthetic, rapidly biodegradable fluid which is based on sustainable raw materials. It is exceptionally suitable for applications in mobile and stationary hydraulic systems. Plahyd N is multigrade hydraulic oil based on rapeseed oil used in agricultural and construction machinery. For thermal parameters measurements was used Hot wire method. The experiment is based on measuring of the temperature rise vs. time evaluation of an electrically heated wire embedded in the tested material. The thermal conductivity is derived from the resulting change in temperature over a known time interval. Dependency of material resistance against the probe rotation was used at measurement of rheologic properties with instrument viscometer Anton Paar DV-3P. For two samples of biooils -Plahyd N and Plahyd S were determined basic thermophysical parameters -thermal conductivity, thermal diffusivity and volume specific heat. For each biooil samples were made two series of measurements. In the first series were measured thermal conductivity and thermal diffusivity at constant room temperature 20 °C. Every thermophysical parameter was measured 10 times for each sample. The results were statistically processed. For biooil No1 thermal conductivity was 0.325 W*m -1 .K -1 , it was higher value than we obtained for biooil No2 -0.224 W*m -1 .K -1 . The similar results were obtained for thermal diffusivity of biooil No1 2.140.10 -7 m 2 *s -1 and biooil No2 2.604.10 -7 m 2* s -1 . For samples with constant temperature were calculated basic statistical characteristics as: standard deviation for -biooil No1 (±0.056 W*m -1* K -1 ) and biooil No2 (± 0.054 W*m -1* K -1 ); probable error of the arithmetic average for -biooil No 1 (±0.012 W*m -1* K -1 ) and biooil No 2 (±0.005 W*m -1* K -1 ); relative probable error in % for -biooil No1 (±3.69 %) and biooil No2 (±2.23 %). The same statistical characteristics were calculated for thermal diffusivity. In the second series of measurements were measured relations of thermal conductivity and thermal diffusivity to the temperature in temperature range (20 -29) °C. From results was evident that all measured dependencies are nonlinear. For both thermophysical parameters were obtained polynomial functions of the second degree described by the polynomial coefficients. Type of function was selected according to statistical evaluation based on the 279
Knowledge of bee products' physical properties has a decisive importance for the monitoring of their quality. Thermophysical parameters are very important properties. Thermal conductivity and thermal diffusivity of selected bee products (honey, bee pollen and perga) were measured by two different methods. For identification of thermal conductivity and thermal diffusivity transient methods were used: Hot Wire (HW) and Dynamic Plane Source (DPS) method with an instrument Isomet 2104. The principle of measuring process is based on the analysis of timetemperature relation. In the first series of measurements thermal conductivity and diffusivity at constant laboratory temperature of 20 °C were measured. The second series was focused on identification of the changes in the thermophysical parameters during temperature stabilisation in the temperature range of 5-25 °C. For samples with constant temperature standard deviations and probable errors in % were calculated. For relations of thermal parameters to temperature graphical dependencies were obtained. Two different thermophysical methods were used for improvement of data reliability and data statistics.
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