The establishment of covalent junctions between carbon nanotubes (CNTs) and the modification of their straight tubular morphology are two strategies needed to successfully synthesize nanotube-based three-dimensional (3D) frameworks exhibiting superior material properties. Engineering such 3D structures in scalable synthetic processes still remains a challenge. This work pioneers the bulk synthesis of 3D macroscale nanotube elastic solids directly via a boron-doping strategy during chemical vapour deposition, which influences the formation of atomic-scale “elbow” junctions and nanotube covalent interconnections. Detailed elemental analysis revealed that the “elbow” junctions are preferred sites for excess boron atoms, indicating the role of boron and curvature in the junction formation mechanism, in agreement with our first principle theoretical calculations. Exploiting this material’s ultra-light weight, super-hydrophobicity, high porosity, thermal stability, and mechanical flexibility, the strongly oleophilic sponge-like solids are demonstrated as unique reusable sorbent scaffolds able to efficiently remove oil from contaminated seawater even after repeated use.
Pristine glass fiber is well known to become mechanically weaker when heat-treated in the presence of water vapor. However, recently, the same fiber was found to become stronger if heat-treated while held under a subcritical tensile stress at a temperature below the glass transition temperature. The added strength was attributed to the formation of a surface compressive layer on the glass created by a surface stress relaxation process that occurred while being held under the tensile stress in air. Silica glass fibers with strengths estimated to be~7-8 GPa were produced, exceeding the~5.5 GPa strength of fresh optical fiber commonly reported at room temperature in air. Similar degrees of strengthening, a 20-30% improvement, have been observed previously for E-glass and is reported here for the first time for soda-lime silicate glasses. This process is a new glass strenthening method that may be applied to all oxide glasses and is not subject to the same constraints as currently available methods.
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