The Yb, ties structural peculiarities and the influence of additional doping of PbW04 crystals with Nb, Bi, and Mg ions have been investigated. It is shown that even a small amount of specific impurileads to an important redistribution of the structural point defects, the radiating centres, and their properties in the crystals. The data have been used for further optimization of PbW04 scintillator development for electromagnetic calorimeter (ECAL) of compact muon solenoid (CMS) at CERN. ') B.P. 110,
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