The electrolyte filling process constitutes the interface between cell assembly and formation of lithium ion batteries. Electrolyte filling is known as a quality critical and also time consuming process step. To avoid limitations in battery quality a homogeneous electrolyte distribution is necessary. Therefore, especially large sized cells are stored for hours. To accelerate filling and wetting processes the effect of materials-and process parameters on electrolyte distribution needs to be investigated. Unfortunately, in situ methods to characterize the filling and wetting state are still rare, limited in availability or even time-consuming in preparation.To overcome these drawbacks this paper introduces X-ray as an innovative method to visualize the electrolyte filling process in large scaled lithium ion batteries. Therefore, an experimental setup was developed to enable in situ X-ray measurements during the filling process of large scaled cells. Additionally, an evaluation process for the optical data was proposed. Based on these images the suitability of X-ray as visualization method is shown considering three exemplary filling parameters.

Electrochemical energy storage combined with renewable energy sources is the sustainable solution to the current energy crisis and mitigation of the geopolitical and environmental consequences resulting from the current dependence on fossil fuels. [1] Early material and technological advances in battery research [2,3] combined with their portability have made batteries the frontrunner in energy storage; from an enabling technology for mobile computing and consumer electronics to the backbone of electric vehicles, large-scale intermittent energy storage, and smart grids. The availability of structured battery data plays a vital role in battery production, development, and application. It can contribute to investigating new electrode materials, optimizing cell design, improving the battery manufacturing process, modifying

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Demand for lithium-ion battery cells (LIB) for electromobility has risen sharply in recent years. In order to continue to serve this growing market, large-scale production capacities require further expansion and the overall effectiveness of processes must be increased. Effectiveness can be significantly optimized through innovative manufacturing technology and by identifying scrap early in the production chain. To enable these two approaches, it is imperative to quantify safety- and function-critical product features in critical manufacturing steps through appropriate measurement techniques. The overview in this paper on quality control in LIB production illustrates the necessity for improved inspection techniques with X-rays to realize a fast, online measurement of inner features in large-scale cell assembly with short cycle times and to visualize inner product-process interactions for the optimization in electrolyte filling. Therefore, two new inspection techniques are presented that contribute to overcoming the aforementioned challenges through the targeted use of X-rays. First, based on the results of previous experiments in which the X-ray beam directions were deliberately varied, a online coordinate measurement of anode-cathode (AC) overhang was developed using a line detector. Second, a new concept and the results of a continuous 2D visualization of the electrolyte filling process are presented, which can be used in the future to optimize this time-critical process step. By using a X-ray-permeable and portable vacuum chamber it is possible to quantify the influence of process parameters on the distribution of the electrolyte in the LIB.