Background: In this research we formulate answers to three important questions related to Givetian carbonate records and their use for reconstructing million-year-scale past palaeoenvironmental changes. First, we provide detailed illustrations of the fascinating diversity that shaped a significant shallow reefal platform during early to late Givetian time in the Rhenohercynian Ocean; secondly we improve the sedimentological model of the extensive Givetian carbonate platform in the Dinant Basin; and thirdly we evaluate the application of magnetic susceptibility as a tool for long-term trend correlations and palaeoenvironmental reconstructions. Methodology/Principal findings: These goals are reached by making a sedimentological, geophysical and geochemical study of the La Thure section. Through the early-late Givetian interval we discerned 18 microfacies ranging from a homoclinal ramp to a discontinuously rimmed shelf and then a drowning shelf. The comparison of these sedimentological results with those published for the south of the Dinant Syncline allowed us to provide an up to date model of the vertical and lateral environmental development of one of the largest Givetian carbonate platforms in Europe. This comparison also increased the knowledge on the distribution of facies belts in the Dinant Basin and allowed us to highlight the Taghanic Event. Palaeoredox proxies reveal a substantial change in the oxygenation level, from oxygen-depleted to more oxic conditions, between middle and late Givetian time. We demonstrated the relationship between variation in magnetic susceptibility values and proxies for siliciclastic input (such as Si, Al). Significance: The La Thure section is considered a key section for the understanding of Givetian paleoenvironmental changes within the internal shelf settings bordering Laurussia's southeastern margin.

The Brilon-reef complex is one of the biggest Devonian carbonate buildups (*80 km 2 ) of the Rheinisches Schiefergebirge. The Burgberg section is located in the southeastern fore-reef area of the Brilon Reef Complex and exposes a succession of strata (117 m thick), which extends from the Middle Givetian (middle varcus conodont Zone) to the Vise ´an (bilineatus conodont Zone). Field and microfacies observations led to the definition of nine microfacies that are integrated into a sedimentary model divided into off-reef, intermediate fore-reef, and proximal fore-reef sedimentary domains (SD). The off-reef domain (SD1) is the most distal setting observed and is characterized by fine-grained sediments, dominated by pelagic biota and the local occurrence of gravity-flow deposits. The intermediate fore-reef (SD2) is characterized by a mixture of biota and sediments coming from both deeper-water and shallow-water sources and is influenced by storm and gravity-flow currents. In this domain, Renalcis moundlike structures developed locally. Finally, the proximal fore-reef (SD3) corresponds to the most proximal setting that is strongly influenced by gravity-flow currents derived from the Brilon Reef Complex. The temporal

The s t r u c t u r e d e t e r m i n a t i o n o f t r o c h e l i o p h o r o l (11, a new cembrane d i t e r p e n e i s o l a t e d f r o m two s o f t c o r a l s of t h e genus Sarcophyton, i s d e s c r i b e d . The t e r p e n o i d c o n t e n t o f s e v e r a l s p e c i e s o f t h e i m p o r t a n t s o f t c o r a l genus Sarcophyta has a l r e a d y been i n v e s t i g a t e d . Red Sea samples o f S. gzaucm were found t o c o n t a i n s a r c o p h i n e and 16-desoxysarcophine as m a j o r compounds [ 3 n 4 ' 5 1 s w h i l e samples of S. trocheliophorm and S. glaucuni f r o m t h e S e y c h e l l e s and I n d o n e s i a c o n t a i n e d t h e c l o s e l y r e l a t e d d e r i v a t i v e s s a r c o p h y t o x i d e o r i s o s a r c o p h y t o x i d e [ 6 ) . Two o f u s (

A succession of Frasnian mounds on the southern border of the Dinant Synclinorium (Belgium) was investigated for their facies architecture, sedimentary dynamics and palaeogeographic evolution. Seven mound facies were defined from the Arche (A) and Lion (L) members, each characterized by a specific range of textures and association of organisms (A2/L2: red or pink limestone with stromatactis, corals and crinoids; A3/L3: grey, pink or green limestone with stromatactis, corals and stromatoporoids; A4/L4: grey limestone with corals, peloids and dasycladaceens; A5/L5: grey microbial limestone; A6/L6: grey limestone with dendroid stromatoporoids; A7/L7: grey laminated limestone with fenestrae; and A8/L8: grey bioturbated limestone). Laterally equivalent sediments include substantial reworked material from the buildups and background sedimentation. Textures and fossils suggest that A2/L2 and A3/L3 facies developed close to storm wave base, in a subphotic environment. Facies A4/L4, occurring near fair weather wave base in the euphotic zone, includes lenses of A5/L5 with stromatolitic coatings and thrombolithes. A6/L6 corresponds to a slightly restricted environment and shows a progressive transition to fenestral limestone of A7/L7. This facies was deposited in a moderately restricted intertidal area. A8/L8 developed in a quiet lagoonal subtidal environment. The mounds started with A2/L2 or A3/L3 in which microbial lenses and algal facies A4/L4 became progressively more abundant upwards. Following 20 m of laterally undifferentiated facies, more restricted facies occur in the central part of the buildups. This geometry suggests the initiation of restricted sedimentation, sheltered by bindstone or floatstone facies. The facies interpretation shows that after construction of the lower part of the mounds during a transgression and a sea-level highstand, a lowstand forced reef growth to the margin of the buildups, initiating the development of atoll-like crowns during the subsequent transgressive stage. The persistence of restricted facies results from the balance between sealevel rise and reef growth.

Recent opening of the La Thure quarry in Western Belgium allowed the collection of new data from a poorly outcropping area of the Belgian Frasnian platform. The studied section covers an interval extending from the falsiovalis to hassi s.l. Zones. Sedimentological analyses allowed the reconstruction of depositional settings in the northwestern part of the Dinant Synclinorium after the demise of the extended Givetian carbonate platform. Two depositional models are distinguished: (a) siliciclastic drowned platform during the Early Frasnian; and (b) a fore-reef depositional setting belonging to a rimmed shelf during the Middle Frasnian. Moreover, interpreted depositional settings in the northwestern part of the Dinant Synclinorium allowed to constraint the direction of the main facies belts for the Belgian Frasnian platform. Combination of MS and geochemistry demonstrates the inherent-parallel link existing between variation in MS values and proxy for terrestrial input (such as Si and Al). This observation means that, despite the remagnetization occurring within the Belgian Frasnian lithologies, the main trends in the MS signal from the La Thure section still reflect some syn-sedimentary conditions. The increase in MS and clastic input proxies recorded in distal fore-reef deposit within the punctata Zone are likely to be considered as enhanced by rapid and strong shallowing events recognized in the ‘puncata Event’ interval.