Absorption spectra of polymer FBT-Th4 (1,4) (M n = 46.4 Kg/mol, E g = 1.62 eV, and HOMO = -5.36 eV) indicate strong interchain aggregation ability. High hole mobilities up to 1.92 cm(2) (V s)(-1) are demonstrated in OFETs fabricated under mild conditions. Inverted solar cells with active layer thicknesses ranging from 100 to 440 nm display PCEs exceeding 6.5%, with the highest efficiency of 7.64% achieved with a 230 nm thick active layer.
Mesoporous TiO 2 (m-TiO 2 ) nanoparticles were used to prepare the porous film electrodes for the dye-sensitized solar cells (DSSCs). The obtained m-TiO 2 porous electrodes were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), electrochemical impedance spectra (EIS), and open-circuit photovoltage decay curves (OCVD). Experimental results indicate that the effect of bulk traps and the surface states within the m-TiO 2 porous films on the recombination processes of the photoinjected electrons in DSSCs depends on the annealing temperature. Moreover, the homemade m-TiO 2 nanoparticles show much higher photoelectric conversion efficiency than the nonporous TiO 2 nanoparticles (P25). The mesostructures within the m-TiO 2 nanoparticles, which can be maintained even after annealing at 500 °C, are of great benefit to the dye adsorption, and then to the improvement of the photoelectrochemical properties of DSSCs.
A new light-emitting polyacetylene bearing imidazole moieties in the side chain (), was conveniently prepared through a postfunctionalization strategy, as a sensory polymer to selectively report the presence of Cu2+ (with a detection limit of 1.48 ppm) based on the fluorescence "turn-off". Interestingly, the quenched luminescence of by Cu2+ could be turned on after the addition of CN-, making a novel, sensitive, and selective cyanide probe.
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