The work concerns the alumina-graphene materials sintered by two different pressure methods. The different particle sizes of graphene were used. The preparation route of the matrix-graphene mixture was discussed in the paper. The so-prepared compositions with different amount of graphene were hot-pressed and spark plasma sintered. The influence on uniaxial pressure during the sintering process on the microstructure was presented by the SEM microstructural observations and ultrasonic measurements. The material with unidirectional oriented graphene particles was prepared, and the anisotropy was even higher than 30 % for 10 mass% of graphene additive. The influence of graphene orientation as an effect of pressing process on the thermal properties was analysed. The anisotropy of thermal conductivity was 90 % for 10 mass% of graphene. The thermal diffusivity and thermal conductivity of composites manufactured by hotpressing and spark plasma sintering method were compared. The experiment-based calculation of the specific heat versus temperature was presented in the paper. The thermal expansion coefficient was determined by dilatometric method. The thermal stability was analysed by thermogravimetric method, and it showed that composites with up to 2 mass% of graphene can work at temperatures higher than 700°C.
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