All-inorganic CsPbX3 perovskite quantum dots have excellent optoelectronic properties and are excellent candidates for optoelectronic applications. However, the surface ligands (oleyl ammonium, oleic acid) commonly used in traditional inorganic perovskite quantum dots easily fall off from the quantum dots and their protective power is relatively weak, resulting in poor quantum yield and stability of the quantum dots, limiting their application. In this paper, we introduce an X-type short-chain ligand (DDEAB) passivation strategy to enhance the optoelectronic properties of CsPbX3 quantum dots through a facile room-temperature synthesis method and the strong affinity of X-type ligands for surface atoms. The results of TRPL and X-ray photoelectron spectroscopy showed longer lifetime and stronger surface affinity. This result confirms that didecyldimethylammonium bromide (DDEAB) has better binding to CsPbBr3 QDs and can effectively reduce surface defects and improve quantum yield. As a result, the introduction of short-chain ligands can more effectively passivate the surface halogen defects of CsPbX3 QDs, achieving high quantum yield (>90%) and long-term storage environmental stability. In addition, DDEAB-passivated CsPbBr3 QDs have been successfully applied in white light emitting diodes (WLEDs) with wider color gamut (123%), and good EL stability compared to NTSC TV color standard. Our proposed short-chain ligand DDEAB passivation strategy may provide a reference guideline for the preparation of quantum dots and photovoltaic devices with high photoluminescence and environmental stability.

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