In
the present study, cobalt manganese phosphate (H-CMP-series)
thin films with different compositions of Co/Mn are prepared on stainless
steel (SS) substrate via a facile hydrothermal method and employed
as binder-free cathode electrodes in a hybrid supercapacitor. The
XRD study reveals a monoclinic crystal structure, and the FE-SEM analysis
confirmed that H-CMP-series samples displayed a nano/microarchitecture
(microflowers to nanoflakes) on the surface of SS substrate with excess
available surfaces and unique sizes. Interestingly, the synergy between
cobalt and manganese species in the cobalt manganese phosphate thin
film electrode demonstrates a maximum specific capacitance of 571
F g–1 at a 2.2 A g–1 current density
in 1 M KOH. Besides, the nano/microstructured cobalt manganese phosphate
was able to maintain capacitance retention of 88% over 8000 charge–discharge
cycles. More importantly, the aqueous/all-solid-state asymmetric supercapacitor
manufactured with the cobalt manganese phosphate thin film as the
cathode and reduced graphene oxide (rGO) as the anode displays a high
operating potential window of 1.6 V. The aqueous asymmetric device
exhibited a maximum specific capacitance of 128 F g–1 at a current density of 1 A g–1 with an energy
density of 45.7 Wh kg–1 and a power density of 1.65
kW kg–1. In addition, the all-solid-state asymmetric
supercapacitor device provides a high specific capacitance of 37 F
g–1 at 1 A g–1 with 13.3 Wh kg–1 energy density and 1.64 kW kg–1 power density in a polymer gel (PVA-KOH) electrolyte. The long cyclic
life of both devices (87 and 84%, respectively, after 6000 cycles)
and practical demonstration of the solid-state device (lighting of
a LED lamp) suggest another alternative choice for cathode materials
to develop stable energy storage devices with high energy density.
Furthermore, the aforementioned study paves the way to investigate
phosphate-based materials as a new class of materials for supercapacitor
applicability.
In the present investigation, microflowers-like hydrous cobalt phosphate is prepared via a facile single-step hydrothermal method on stainless steel substrate. The microflowers-like morphology of hydrous cobalt phosphate thin film consists of microplates and further microplates converted to flakes by means of a change in length, width, and thickness with urea variation. Hydrous cobalt phosphate thin film electrode demonstrates a high specific capacitance of 800 F g −1 at 2 mA cm −2 with 33.62 Wh kg −1 energy density and 3.12 kW kg −1 power density. By taking advantage of hydrous cobalt phosphate thin film (as a cathode electrode) and copper sulfide thin film (as an anode electrode), the asymmetric devices (aqueous/all-solid-state) are fabricated. Aqueous asymmetric device shows a high specific capacitance of 163 F g −1 at 2 mA cm −2 with an energy density of 58.12 Wh kg −1 and power density of 3.52 kW kg −1 . Moreover, the all-solid-state asymmetric supercapacitor device delivers a high specific capacitance of 70 F g −1 at 2 mA cm −2 with 24.91 Wh kg −1 energy density and 2.63 kW kg −1 power density in PVA−KOH gel electrolyte. The long-term cyclic stability (94% after 3000 cycles) and actual practical demonstration (lightning 65 red LEDs) suggest an industrial application of the allsolid-state asymmetric device.
Hydrous nickel sulphide is successfully synthesized on graphene foam (Ni9S8/GF) using a facile chemical bath deposition (CBD) method for supercapacitor application.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.