The treatment of wastewater is an expensive and energy-extensive practice that not only ensures the power generation requirements to sustain the current energy demands of an increasing human population but also aids in the subsequent removal of enormous quantities of wastewater that need to be treated within the environment. Thus, renewable energy source-based wastewater treatment is one of the recently developing techniques to overcome power generation and environmental contamination issues. In wastewater treatment, microbial fuel cell (MFC) technology has demonstrated a promising potential to evolve as a sustainable approach, with the simultaneous recovery of energy and nutrients to produce bioelectricity that harnesses the ability of electrogenic microbes to oxidize organic contaminants present in wastewater. Since traditional wastewater treatment has various limitations, sustainable implementations of MFCs might be a feasible option in wastewater treatment, green electricity production, biohydrogen synthesis, carbon sequestration, and environmentally sustainable sewage treatment. In MFCs, the electrochemical treatment mechanism is based on anodic oxidation and cathodic reduction reactions, which have been considerably improved by the last few decades of study. However, electricity production by MFCs remains a substantial problem for practical implementations owing to the difficulty in balancing yield with overall system upscaling. This review discusses the developments in MFC technologies, including improvements to their structural architecture, integration with different novel biocatalysts and biocathode, anode, and cathode materials, various microbial community interactions and substrates to be used, and the removal of contaminants. Furthermore, it focuses on providing critical insights and analyzing various types, processes, applications, challenges, and futuristic aspects of wastewater treatment-related MFCs and thus sustainable resource recovery. With appropriate planning and further studies, we look forward to the industrialization of MFCs in the near future, with the idea that this will lead to greener fuels and a cleaner environment for all of mankind.

In the past few years, microalgae have gained huge recognition from the scientific community due to their potential applications in the production of a broad array of bio‐based products varying from biofuels to nanoparticles. Due to their elevated growth rate, high tolerance to various types of abiotic stresses, and complex metabolic capacity, microalgae can be used as promising tools for the attainment of a circular bioeconomy. Moreover, they can simply utilize nutrients from wastewater for biorefinery purposes, resulting in resource recovery coupled with wastewater treatment. However, due to their sub‐optimal yields and high production costs, microalgae‐based bio‐products have not yet been commercialized. This review provides insights into the employment of microalgae as an efficient bioresource for the treatment of wastewater with simultaneous enactment as a biorefinery to produce biofuels, biochar, bioplastic, fertilizers, and other high‐value bioproducts. Furthermore, the application of microalgal nanoparticles in wastewater treatment and prospects for genetic modification of microalgae for enhanced biorefinery capabilities have also been briefly highlighted.