The influence of the solvent type on the rheological properties of Carbopol ® NF 980 dispersions in water and in water/glycerol solutions is investigated. The material formulation, preparation procedure, common experimental challenges and artifact sources are all addressed. Transient and steady-state experiments were performed. For both solvent types, a clearly thixotropic behavior occurs slightly above the yield stress, where the avalanche effect is observed. For larger stresses, thixotropy is always negligible. Among other findings, it is observed that, for a given Carbopol concentration, the dispersion in the more viscous solvent possesses a lower yield stress and moduli, a larger power-law index, and a longer time to reach steady state.

No abstract

We experimentally studied the viscous fingering instability considering a Newtonian oil displacing viscoelastic shear-thinning liquids and vice versa. The non-Newtonian liquids are aqueous solutions of polyacrylamide and xanthan gum, i.e., flexible and rigid polymers, respectively. A rectangular Hele-Shaw cell, connected by two plenum chambers, was developed to evaluate the displacement of a fixed volume. The experiment consists of analyzing the interface time evolution through a digital camera as a function of the geometric, dynamic, and rheological parameters. The displacement efficiency was determined through image processing in order to identify the formation of fingers or plugs. Unlike the Newtonian case, the transition does not occur when the viscosity ratio is roughly equal to one, but nevertheless, it was observed that the stability of the interface depends on the viscosity ratio. Specifically, more branches are observed at low viscosity ratios. Furthermore, a higher stability is observed when the Newtonian liquid displaces the shear thinning liquid, especially when the polymer is more rigid. When the Newtonian liquid is being displaced, elastic effects favor the displacing efficiency.

No abstract

We present an experimental study of the flow of yield stress materials through annular abrupt expansions–contractions, to evaluate the flow invasion into the cavity formed in the larger cross section region. Steady inertialess flows of Carbopol® aqueous dispersions were investigated. The flow pattern reveals yielded and unyielded regions, which were visualized using tracer particles, laser sheets, and a digital camera. The yield surfaces were identified in the experiments by choosing large enough exposure times that allow sufficient particle displacement in the yielded region. To estimate the amount of fluid that remains stagnant in the cavity, we defined the invasion ratio, a quantity that was determined through image processing for different combinations of the governing parameters. The influence of the cavity diameter and axial length, eccentricity, and inlet velocity on the invasion ratio was investigated. Fore-aft asymmetric yield surfaces were observed for all tests, probably due to elastic effects.