Magnetic nanoparticles (NPs) have been used to separate various species such as bacteria, cells, and proteins. In this study, we synthesized Ag/FeCo/Ag core/shell/shell NPs designed for magnetic separation of subcellular components like intracellular vesicles. A benefit of these NPs is that their silver metal content allows plasmon scattering to be used as a tool to observe detection by the NPs easily and semipermanently. Therefore, these NPs are considered a potential alternative to existing fluorescent probes like dye molecules and colloidal quantum dots. In addition, the Ag core inside the NPs suppresses the oxidation of FeCo because of electron transfer from the Ag core to the FeCo shell, even though FeCo is typically susceptible to oxidation. The surfaces of the Ag/FeCo/Ag NPs were functionalized with ε-poly-L-lysine-based hydrophilic polymers to make them water-soluble and biocompatible. The imaging capability of the polymer-functionalized NPs induced by plasmon scattering from the Ag core was investigated. The response of the NPs to a magnetic field using liposomes as platforms and applying a magnetic field during observation by confocal laser scanning microscopy was assessed. The results of the magnetophoresis experiments of liposomes allowed us to calculate the magnetic force to which each liposome was subjected.

Missing-cluster defects in Zr-based UiO-66 can be generated by rigorous control of water without the need of acidic modulators.

The formation mechanism of Ag@FeCo@Ag core–shell–shell nanoparticles which are synthesized by the combination of a multi-step hot injection method and a polyol method was investigated by comparing several different derivative NPs such as Ag@FeCo, Ag@Co, Ag@Fe and FeCo NPs.

Combining Au and Fe into a single nanoparticle is an attractive way to engineer a system possessing both plasmonic and magnetic properties simultaneously. However, the formation of the AuFe alloy is challenging because of the wide miscibility gap for these elements. In this study, we synthesized AuFePt ternary alloy nanoparticles as an alternative to AuFe alloy nanoparticles, where Pt is used as a mediator that facilitates alloying between Au and Fe in order to form ternary alloy nanoparticles. The relationship among composition, structure, and function is investigated and it was found that at an optimized composition (AuFePt), ternary alloy NPs exhibit both magnetic and plasmonic properties simultaneously. The plasmonic properties are investigated in detail using a theoretical Mie model, and we found that it is governed by the dielectric constant of the resulting materials.

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