Gas sensors that are highly sensitive, stable, and selective are increasingly in demand to detect toxic gases. As a result of the need to monitor concentrations of these gases, humans, animals, and the environment are all protected. Metal ferrites (AFe2O3, where A is a metal) are a major factor in this field. The development of ferrite gas sensors has made remarkable advances in the detection of toxic gases from vehicle exhaust, biological hazards, environmental monitoring, and pollution monitoring over the last decade. It is important for ferrite gas sensors to consider parameters like phase formation, crystallite size, particle size, grain size, dopants, surface area, sensitivity, selectivity, operating temperature, gas concentration, response time, and recovery time. There are various materials for gas sensing use such as carbon monoxide (CO), carbon dioxide (CO2), methane (CH4), ethyl alcohol (C2H5OH), hydrogen sulfide (H2S), C2H5COOH, oxygen (O2), hydrogen (H2), chlorine (Cl2), NH3, C4H10, CH3COOH, gasoline, acetylene, petrol, and liquefied petroleum gas (LPG). Various methods are used to prepare ferrite gas sensors. Additionally, a brief description is provided of the various methods employed for synthesizing ferrite gas sensors. A comprehensive survey of ferrites as gas sensors, such as nickel, copper, zinc, cadmium, cobalt, magnesium, manganese, and multi-component ferrites, prepared by various methods.
The oxalate co-precipitation method was used to prepare nanocrystallite ferrites with Nd 3+ added to the general formula Mg1 -xCdxFe2O4 (x 0.5). FTIR, XRD, and SEM were all used to characterize the samples. According to XRD, the structure is cubic spinel with orthoferrite (NdFeO3) as a secondary phase. The crystallite size is 36.79 nm. SEM analysis of surface morphology indicates a grain size of 0.38 m. There are two strong absorption bands observed in the FTIR spectrum in the range of 350-800 cm -1 . We were able to detect various gases such as Cl2, LPG, and ethanol using the gas sensor from room temperature to 500 C. For 100 ppm ethanol gas at 500 C, the Mg0.5Cd0.5Nd0.01Fe1.99O4 composition has the greatest response. Mg-Cd ferrite sensor samples with Nd 3+ added show good response and recovery time. Material composition, test gas, and grain size determine the time to complete the test.
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