The presence of dispersed inclusions is known to modify the interfacial characteristics in liquids by adsorption–desorption of the ions at interfaces. The present article reports the influencing role of dissolved ions in a polar fluid on its evaporation dynamics. The evaporation dynamics of pendant droplets of aqueous solutions of variant simple salts and concentrations have been experimentally studied. The presence of salts is observed to enhance the evaporation rate (obeying the classical D2 law), and the enhancement has been found to hold a direct proportionality to the concentration of the dissolved salt. Furthermore, it is observed that the degree of enhancement in the evaporation rate is also directly proportional to the solubility of the salt in question. The phenomenon is explained based on the chemical kinetics and thermodynamics of hydration of the ionic species in the polar fluid. The classical evaporation rate constant formulation is found to be inadequate in modeling the enhanced species transport. Additional probing via particle image velocimetry reveals augmented internal circulation within the evaporating salt based drops compared to pure water. Mapping the dynamic surface tension reveals that a salt concentration gradient is generated between the bulk and periphery of the droplet and it could be responsible for the internal advection cells visualized. A thermo-solutal Marangoni and Rayleigh convection based mathematical formulation has been put forward, and it is shown that the enhanced solute-thermal convection could play a major role in enhanced evaporation. The internal circulation mapped from experiments is found to be in good quantitative agreement with the model predictions. Scaling analysis further reveals that the stability of the solutal Marangoni convection surpasses the thermal counterpart with higher salt concentration and solubility. The present article sheds insight into the possible domineering role of conjugate thermohydraulic and mass transport phenomena on the evaporation kinetics aqueous droplets with ionic inclusions.

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A systematically designed study has been conducted to understand and demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles and the combined effects of these on the surface tension of these complex fluids are studied employing the pendant drop shape analysis method by fitting the Young-Laplace equation. Only the particle has shown an increase in the surface tension with particle concentration in a polar medium like DI water, whereas only a marginal effect of particles on surface tension in weakly polar mediums like glycerol and ethylene glycol has been demonstrated. Such behaviour has been attributed to the enhanced desorption of particles to the interface and a theory has been presented to quantify this. The combined particle and surfactant effect on the surface tension of a complex nanofluid system showed a decreasing behaviour with respect to the particle and surfactant concentration with a considerably feeble effect of particle concentration. This combined colloidal system recorded a surface tension value below the surface tension of an aqueous surfactant system at the same concentration, which is a counterintuitive observation as only the particle results in an increase in the surface tension and only the surfactant results in a decrease in the surface tension. The possible physical mechanism behind such an anomaly happening at the complex fluid air interface has been explained. Detailed analyses based on thermodynamic, mechanical and chemical equilibrium of the constituents and their adsorption-desorption characteristics as extracted from the Gibbs adsorption analysis have been provided. The present paper conclusively explains several physical phenomena observed, yet hitherto unexplained, in the case of the surface tension of such complex fluids by segregating the individual contributions of each component of the colloidal system.

Droplet deposition after impact on superhydrophobic surfaces has been an important area of study in recent years due to its potential application in reduction of pesticides usage. Minute amounts of long chain polymers added to water has been known to arrest the droplet rebound effect on superhydrophobic surfaces. Previous studies have attributed different reasons like extensional viscosity, dominance of elastic stresses or slowing down of contact line in retraction phase due to stretching of polymer chains. The present study attempts to unravel the existence of critical criteria of polymer concentration and impact velocity on the inhibition of droplet rebound. The impact velocity will indirectly influence the shear rate during the retraction phase, and the polymer concentration dictates the relaxation timescale of the elastic fluids. Finally we show that the Weissenberg number (at onset of retraction), which quantifies both the elastic effects of polymer chains and the hydrodynamics, is the critical parameter in determining the regime of onset of rebound suppression, and that there exists a critical value which determines the onset of bounce arrest. The previous three causes, which are manifestations of elastic effects in non-Newtonian fluids, can be related with the proposed Weissenberg number criterion.

Evaporation kinetics of pendant droplets is an area of immense importance in several applications, in addition to possessing rich fluid dynamics and thermal transport physics. This article experimentally and analytically sheds insight into the augmented evaporation dynamics of paramagnetic pendant droplets in the presence of a magnetic field stimulus. The literature provides information that solutal advection and the solutal Marangoni effect lead to enhanced evaporation in droplets with solvated ions. The main focus of this article is to modulate the thermosolutal advection with the aid of an external magnetic field and comprehend the dynamics of the evaporation process under such complex multiphysics interactions. Experimental observations reveal that the evaporation rate enhances as a direct function of the magnetic moment of the solvated magnetic element ions, thereby pointing at the magnetophoretic and magnetosolutal advection. Additionally, flow visualization by particle image velocimetry illustrates that the internal advection currents within the droplet increase in magnitude and are distorted in orientation by the magnetic field. A mathematical formalism based on magnetothermal and magnetosolutal advection has been proposed via scaling analysis of the species and energy conservation equations. The formalism takes into account all major governing factors, viz., the magnetothermal and magnetosolutal Marangoni numbers, magneto-Prandtl and magneto-Schmidt numbers, and the Hartmann number. The modeling establishes the magnetosolutal advection to be the dominant factor behind the augmented evaporation dynamics. Accurate validation of the experimental internal circulation velocity is obtained from the proposed model. This study reveals rich insight into the magnetothermosolutal hydrodynamics in paramagnetic droplets.